# US 4,391,970 A · Process for preparing colorless hydroxyl epihalohydrin polymers

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- Number: US 4,391,970 A
- Document ID: US4391970A
- Status: Granted
- Kind: A
- Application number: 06/375,243
- Filed: 1982-05-06
- Granted: 1983-07-05
- Earliest claimed: 1982-05-06
- Assignees: The B. F. Goodrich Company
- Inventors: Yoshihisa Okamoto
- Web page: https://patentgrep.com/patent/US4391970A

## CPC

- C08G 65/105: {Onium compounds}
- C08G 18/5006: {having chlorine and/or bromine atoms}
- C08G 65/24: Epihalohydrins
- C08G 65/30: Post-polymerisation treatment, e.g. recovery, purification, drying
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

## Abstract

In a process for the polymerization of an epihalohydrin wherein the catalyst (initiator) employed is a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is a Group V element selected from the group consisting of phosphorus, arsenic and antimony, and the polymerization is conducted in the presence of controlled amounts of water or a polyol to obtain hydroxyl containing low molecular weight polymers, a colorless polymer is obtained when the reaction product is washed with an aqueous solution of an alkal metal carbonate.

## Claims

### Claim 1

In a process for the manufacture of hydroxyl-terminated polymers which comprises polymerizing an epihalohydrin in the presence of from about 0.03 part to 15.0 parts by weight of water or polyol, based on 100 parts by weight of the epihalohydrin, and catalytic amounts of a trialkyl oxonium salt of an HMF.sub.6 acid wherein M is an element selected from the group consisting of phosphorus, arsenic and antimony, the improvement comprising washing the polymer with an aqueous solution of an alkali metal carbonate, the amount of said metal carbonate being a molar excess over the amount of said catalyst, at a temperature of greater than 40.degree. C., whereby there is obtained a clear, colorless, heat stable polymer having a pH of about 5 to 8.

### Claim 2 (depends on 1)

A process of claim 1 wherein the epihalohydrin is epichlorohydrin.

### Claim 3 (depends on 2)

A process of claim 2 wherein the polyol is an alkane diol or triol, the hydroxyl groups are primary or secondary and at least one is primary, and the polyol contains 2 to 8 carbon atoms.

### Claim 4 (depends on 3)

A process of claim 3 wherein HMF.sub.6 is HPF.sub.6.

### Claim 5 (depends on 4)

A process of claim 4 wherein said carbonate is sodium bicarbonate present in a molar ratio of greater than nine to one of catalyst.

### Claim 6 (depends on 5)

A process of claim 5 wherein the polymer is washed at temperatures and times substantially equivalent to 50.degree. C. to 100.degree. C. and about one half to one hour to obtain a substantially neutral polymer.

### Claim 7 (depends on 6)

A process of claim 6 wherein the polymer is washed at about 70.degree. C. for about one half to one hour with about 9 to 18 mols of sodium bicarbonate to one mol of catalyst.