# US 4,391,934 A · Dry textile warp size composition > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,391,934 A - Document ID: US4391934A - Status: Granted - Kind: A - Application number: 06/213,328 - Filed: 1980-12-05 - Granted: 1983-07-05 - Earliest claimed: 1980-12-05 - Assignees: ABCO Industries, Ltd. - Inventors: David J. Lesley; Lawrence C. Davis, Jr. - Web page: https://patentgrep.com/patent/US4391934A ## CPC - D06M 15/507: Polyesters - Y10T 442/3049: Including strand precoated with other than free metal or alloy - D06M: TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract A dry textile warp size composition for use in the sizing of yarns containing natural fibrous materials, synthetic fibrous materials, or blends of same including a polyester in particulate form, a film former, and optionally a lubricant and other minor additives. The polyester is preferably rendered into particulate form by grinding at reduced temperature, includes anionic hydrophilic groups and is at least substantially saturated. A process for producing the size composition is also disclosed and claimed. ## Claims ### Claim 1 A dry textile warp size composition for yarns that contains synthetic or natural fibrous materials comprising a blend of a polyester resin, said resin including ionic hydrophilic groups therein, said resin further being at least substantially saturated, and in particulate form, and a film former, said blend being at least water dispersible and the particulate polyester resin in said blend being at least substantially non-adherent to adjacent polyester resin particles. ### Claim 2 (depends on 1) The warp size composition as defined in claim 1 wherein the polyester is present in an amount in a range of from about 10 to about 60 weight percent. ### Claim 3 (depends on 1) The warp size composition as defind in claim 1 wherein the polyester is anionic in nature and the composition further comprises a carboxyl neutralizing agent adequate to achieve desired dispersibility. ### Claim 4 (depends on 1) The composition as defined in claim 1 further comprising a lubricant. ### Claim 5 (depends on 1) The composition as defined in claim 1 wherein hydrophilic groups of the polyester are anionic and are selected from the class consisting of alkali salts of carboxylates, sulfates, sulfonates and phosphates. ### Claim 6 (depends on 1) The composition as defined in claim 1 wherein the hydrophilic groups of the polyester are cationic and are selected from the group consisting of quaternary sulfates and quaternary ammonium chloride. ### Claim 7 A dry textile warp size composition comprising: (a) from about 5 to about 90 weight percent of a polyester resin, said polyester including anionic hydrophilic groups thereon, being at least substantially saturated, and being in particulate form; (b) from about 5 to about 90 weight percent of a film former; (c) an amount of a neutralizing agent necessary to achieve dispersibility in an aqueous medium; and (d) optionally, a small amount of a defoamer. ### Claim 8 (depends on 1, 7) The composition as defined in claims 1 or 7 wherein the polyester is produced from diethylene glycol, isophthalic acid and trimellitic anhydride, and has an acid value of from about 20 to about 100. ### Claim 9 (depends on 1, 7) The composition as defined in claims 1 or 7 wherein the film former is at least one member selected from a group consisting of starch, carboxymethyl cellulose, and polyvinyl alcohol. ### Claim 10 (depends on 7) The composition as defined in claim 7 further comprising up to about 20 weight percent of a lubricant. ### Claim 11 (depends on 1, 7) The composition as define in claim 1 or 7 wherein the polyester resin is ground to a particle size no larger than about 5 mesh, U.S. Standard Sieve size. ### Claim 12 A process for producing a textile warp size composition for yarns that contain synthetic or natural fibrous material or blends of same comprising the steps of: (a) providing a polyester resin that is at least substantially saturated, said resin having ionic hydrophilic groups thereon; (b) rendering said resin particulate in form, said particles being of a size to permit dispersion of same in an aqueous medium; and (c) mixing a predetermined amount of a film former with said particulate resin adequate to achieve a blend of ingredients in which the resin particles will not agglomerate under normal shipping and storage conditions. ### Claim 13 (depends on 12) The process as defined in claim 12 wherein the polyester resin is prepared by reacting diethylene glycol, isophthalic acid and trimellitic anhydride in presence of a suitable catalyst at temperatures in a range of from about 400.degree. to about 450.degree. F. until an acid value of from about 20 to about 100 is achieved. ### Claim 14 (depends on 12) The process as defined in claim 12 wherein in addition to the film former, a carboxyl neutralizing agent and a defoamer are mixed with the polyester resin. ### Claim 15 (depends on 14) The process as defined in claim 14 wherein further, a lubricant is mixed with the other ingredients. ### Claim 16 (depends on 12) The process as defined in claim 12 wherein the polyester resin is cryogenically ground at a temperature at least as low as 0.degree. F. ### Claim 17 (depends on 16) The process as defined in claim 16 wherein the grinding temperature is below -50.degree. F. ### Claim 18 (depends on 16) The process as defined in claim 16 wherein the film former is mixed with the particulate polyester resin immediately after grinding. ### Claim 19 (depends on 16) The process as defined in claim 16 wherein the film former is mixed with the polyester resin during grinding of the polyesters. ### Claim 20 (depends on 12) The process as defined in claim 12 wherein a carboxyl neutralizing agent, a defoamer and a wax are also mixed with the granular polyester resin. ### Claim 21 (depends on 12) The process as defined in claim 12 wherein 20 weight percent polyester, 79 weight percent starch, 0.25 weight percent soda ash and 0.25 weight percent of a defoamer are mixed. ### Claim 22 (depends on 12) The process as defined in claim 12 wherein the film former is selected from a group consisting of starch, carboxymethyl cellulose, polyvinyl alcohol, and mixtures of same. ### Claim 23 (depends on 12, 13) The process as defined in claims 12 or 13 wherein said resin is ground into particulate form.