# US 4,391,921 A · Elastomeric silicone sponge

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 4,391,921 A
- Document ID: US4391921A
- Status: Granted
- Kind: A
- Application number: 06/391,898
- Filed: 1982-06-25
- Granted: 1983-07-05
- Earliest claimed: 1982-06-25
- Assignees: Dow Corning Corporation
- Inventors: Robert D. Johnson
- Web page: https://patentgrep.com/patent/US4391921A

## CPC

- C08J 9/28: by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J 2383/04: Polysiloxanes
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)

## Abstract

A method of producing silicone elastomeric sponge is disclosed. The method comprises freezing an aqueous silicone emulsion, then thawing and drying to produce a silicone sponge containing irregular closed cells. The aqueous silicone emulsion comprises water, an anionically stabilized hydroxyl endblocked polydiorganosiloxane, an organic tin compound, and a colloidal silica, the emulsion having a pH of from 9 to 11.5 inclusive. The sponge produced by the method is useful as insulation and gasketing at high and low temperatures.

## Claims

### Claim 1

A method comprising
(a) freezing a silicone emulsion which provides an elastomeric product upon removal of the water, having a pH in the range of 9 to 11.5 inclusive, comprising water, 100 parts by weight of an anionically stabilized hydroxyl endblocked polydiorganosiloxane having an average molecular weight of greater than 10,000, an organic tin compound, and at least one part by weight colloidal silica, long enough to freeze the water and produce a solid frozen article,
(b) thawing the solid frozen article yielding a wet elastomeric sponge-like article, and
(c) drying the wet elastomeric sponge-like article until the water is removed and an elastomeric sponge is obtained.

### Claim 2 (depends on 1)

The method according to claim 1 further comprising mechanically mixing air into the emulsion prior to freezing step (a).

### Claim 3 (depends on 1)

The method according to claim 1 wherein the emulsion defined in step (a) also contains an organic amine, a thickener, and a filler other than colloidal silica.

### Claim 4 (depends on 1)

The method according to claim 1 wherein the colloidal silica is present in an amount from 10 to 50 parts by weight.

### Claim 5 (depends on 1)

The method according to claim 1 wherein the drying step (c) comprises exposing the wet sponge-like article to ambient air.

### Claim 6 (depends on 1)

The method according to claim 1 wherein the drying step (c) comprises heating the wet sponge-like article.

### Claim 7 (depends on 6)

The method according to claim 6 wherein the thawing step comprises heating the solid frozen article.

### Claim 8 (depends on 1)

The method according to claim 1 wherein the polydiorganosiloxane is polydimethylsiloxane and the organic tin compound is a dialkyltindicarboxylate present in an amount of from 0.1 to 2 parts by weight for each 100 parts by weight polydiorganosiloxane.

### Claim 9 (depends on 8)

The method according to claim 8 wherein the emulsion defined in step (a) also contains an organic amine, a thickener and filler other than colloidal silica.

### Claim 10 (depends on 9)

The method according to claim 9 further comprising mechanically mixing air into the emulsion prior to freezing step (a).

### Claim 11 (depends on 10)

The method according to claim 10 wherein the drying step (c) comprises exposing the wet sponge-like article to ambient air.

### Claim 12 (depends on 10)

The method according to claim 10 wherein the drying step (c) comprises heating the wet sponge-like article.

### Claim 13 (depends on 12)

The method according to claim 12 wherein the thawing step comprises heating the solid frozen article.