# US 4,391,855 A · Corrosion resistant coating and method for coating metal substrate > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,391,855 A - Document ID: US4391855A - Status: Granted - Kind: A - Application number: 06/372,980 - Filed: 1982-04-29 - Granted: 1983-07-05 - Earliest claimed: 1980-08-25 - Assignees: Depor Industries - Inventors: Thurlow Geeck - Web page: https://patentgrep.com/patent/US4391855A ## CPC - C09D 163/00: Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins - C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D) ## Abstract A coating and method of protecting a metal substrate from corrosion by applying a thin film of a liquid composition on the substrate and heating the wet film to an elevated temperature for a period of time to dry or cure the film and thereby adhere a protective coating to the substrate without the maximum temperature of the substrate exceeding about 500.degree. F. and preferably 450.degree. F. The composition contains a primary corrosion inhibitor of powdered metal dispersed in a bonding material of linear epoxy or phenoxy resin and a vehicle of active and inactive organic solvents. Preferably, the composition also includes secondary corrosion inhibiting resins, a thioxotropic material, a hygroscopic material, a powdered metal suspension agent, and a material to neutralize the acidity of the linear epoxy or phenoxy resin. ## Claims ### Claim 1 A corrosion resistant coating for application to and curing at an elevated temperature on a metal substrate comprising: powdered metal selected from the group consisting essentially of zinc, cadmium, stainless steel, aluminum, and alloys and blends thereof; said powdered metal having an average particle size not greater than about 40 microns and a maximum particle size not greater than about 100 microns; a resin system at least 80% by weight consisting essentially of thermoplastic linear phenoxy resin having a high molecular weight in the range of about 3,000 to 60,000 and essentially no highly reactive terminal epoxy groups, the balance of said resin system consisting essentially of formaldehyde, melamine, phenolic, and triazine resins and blends thereof; the quantity of said resin system being about 10% to 525% by weight of said powdered metal; active organic solvent selected from the group consisting essentially of acetone, cellosolve acetate, methyl ethyl ketone, methyl isobutyl ketone, dimethylformamide, and blends thereof; inactive organic solvent selected from the group consisting essentially of aromatic hydrocarbons, alcohols, and blends thereof in a quantity equal to about 0.1 to 0.4 by weight of said active organic solvent; and the total quantity of said organic solvents being sufficient for the composition to have a viscosity in the range of about 20 to 280 seconds with a Ford No. 4 cup. ### Claim 2 (depends on 1) The composition of claim 1 wherein said balance of said resin system consists essentially of melamine formaldehyde, urea-formaldehyde, hexomethoxmethyl-melamine, phenolic, and triazine resins and blends thereof. ### Claim 3 (depends on 1) The coating of claim 1 which also comprises a quantity of polyethylene equal to about 0.2% to 0.5% by weight of said powdered metal. ### Claim 4 (depends on 1) The coating of claim 1 which also comprises a quantity of a hygroscopic agent equal to about 0.2% to 12% by weight of said powdered metal. ### Claim 5 (depends on 1) The coating of claim 1 which also comprises a quantity of a hygroscopic agent equal to about 0.2% to 12% by weight of said powdered metal, said hygroscopic agent being selected from the group consisting essentially of calcium oxide, silica dioxide, barium oxide, and potassium chloride. ### Claim 6 (depends on 1) The coating of claim 1 which also comprises a quantity of thixotropic agent equal to about 0.4% to 12% by weight of said powdered metal. ### Claim 7 (depends on 1) The composition of claim 1 which also comprises a quantity of a silane treated silica dioxide thixotropic agent equal to about 0.4% to 12% by weight of said powdered metal. ### Claim 8 (depends on 1) The composition of claim 1 which also comprises sufficient thixotropic agent to maintain said powdered metal in a colloidal suspension. ### Claim 9 (depends on 1) The composition of claim 1 wherein said powdered metal has an average particle size not greater than about 10 microns. ### Claim 10 (depends on 1) The composition of claim 1 which also comprises sufficient calcium oxide to essentially neutralize the acidity of said liner phenoxy resin. ### Claim 11 A method of protecting a metal substrate from corrosion comprising: applying to at least a portion of the surface of the substrate a thin and wet film of a liquid composition comprising powdered metal selected from the group consisting essentially of zinc, cadmium, stainless steel, aluminum, and alloys and blends thereof; said powdered metal having an average particle size not greater than about 40 microns and a maximum particle size not greater than about 100 microns; a resin system at least 80% by weight consisting essentially of a thermoplastic linear phenoxy resin having a high molecular weight in the range of about 3,000 to 60,000 and essentially no highly reactive terminal epoxy groups, the balance of said resin system consisting essentially of formaldehyde, melamine, phenolic, and triazine resins and blends thereof; the quantity of said resin system being about 10% to 525% by weight of said powdered metal; active organic solvent selected from the group consisting essentially of acetone, cellosolve acetate, methyl ethyl ketone, methyl isobutyl ketone, dimethylformamide, and blends thereof; inactive organic solvent selected from the group consisting essentially of aromatic hydrocarbons, alcohols, and blends thereof in a quantity equal to about 0.1 to 0.4 by weight of said active organic solvent; the total quantity of said organic solvents being sufficient for the composition to have a viscosity in the range of about 20 to 280 seconds with a Ford No. 4 cup; and heating the thin wet film to an elevated temperature for a sufficient period of time to evaporate the solvents and thereby tenaciously adhere the film to the substrate as a coating protecting the substrate from corrosion without heating any portion of the substrate to a temperature greater than 450.degree. F. ### Claim 12 (depends on 11) The method of claim 11 wherein the thickness of the wet film of the composition applied to the substrate is not greater than about 3 mils. ### Claim 13 (depends on 11) The method of claim 11 wherein the thickness of the wet film applied to the substrate is not greater than about 3 mils and the thickness of the cured film on the substrate is not greater than about 0.8 of a mil. ### Claim 14 (depends on 11) The method of claim 11 wherein the wet film on the substrate is heated to an elevated temperature for a period of time in the range of about 40 minutes to 30 seconds and the maximum temperature of the substrate is in the range of about 300.degree. F. ### Claim 15 The method of making a corrosion resistant coating for application to and curing at an elevated temperature on a metal substrate comprising: mixing together powdered metal having an average particle size not greater than about 40 microns and a maximum particle size not greater than about 100 microns, said powdered metal being selected from the group consisting essentially of zinc, cadmium, stainless steel, aluminum, and alloys and blends thereof; a resin system at least 80% by weight consisting essentially of a thermoplastic linear phenoxy resin having a high molecular weight in the range of about 3,000 to 60,000 and essentially no highly reactive terminal epoxy groups, the balance of said resin system consisting of formaldehyde, melamine, phenolic, and triazine resins and blends thereof; the quantity of said resin system being equal to about 10% to 525% by weight of said powdered metal, and a quantity of active solvent equal to about one to two times the weight of the linear phenoxy resin; agitating the mixture of powdered metal, linear phenoxy resin, and organic solvent, while elevating its temperature to 120.degree. F. to 180.degree. F.; milling the heated mixture to produce a homogeneous mixture having a Hegman grind rating in the range of 4.5 H to 7.5 H; and thereafter, blending the homogeneous mixture with a sufficient quantity of active and inactive organic solvents sufficient for the final blend to have a viscosity in the range of about 20 to 280 seconds with a Ford No. 4 cup; said active organic solvent being selected from the group consisting of acetone, cellosolve acetate, methyl ethyl ketone, methyl isobutyl ketone, dimethylformamide and blends thereof, and said inactive solvent being selected from the group consisting essentially of aromatic hydrocarbons, alcohols, and blends thereof in a quantity equal to about 0.1 to 0.4 by weight of said active organic solvent. ### Claim 16 (depends on 15) The method of claim 15 wherein said balance of said resin system consists essentially of melamine formaldehyde, urea formaldehyde, hexomethoxymethyl melamine, phenolic, and triazine resins and blends thereof. ### Claim 17 (depends on 15) The method of claim 15 which also comprises including in the initial mixture of powdered metal, epoxy resin, and organic solvent, a quantity of thixotropic material equal to about 0.4% to 12% by weight of said powdered metal. ### Claim 18 (depends on 15) The method of claim 15 which also comprises including in the initial mixture of powdered metal, epoxy resin, and organic solvent, a quantity of a saline treated silica thixotropic agent equal to about 0.4% to 12% by weight of said powdered metal. ### Claim 19 (depends on 15) The method of claim 15 which also comprises including in the initial mixture of powdered metal, linear phenoxy resin and organic solvent, sufficient calcium oxide to essentially neutralize the acidity of the linear phenoxy resin.