# US 4,391,838 A · Process for continuous fluidization of shortening > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 4,391,838 A - Document ID: US4391838A - Status: Granted - Kind: A - Application number: 06/320,860 - Filed: 1981-11-13 - Granted: 1983-07-05 - Earliest claimed: 1981-11-13 - Assignees: SCM Corporation - Inventors: Daniel R. Pate - Web page: https://patentgrep.com/patent/US4391838A ## CPC - A23D 9/02: characterised by the production or working-up - A23D: EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS (preservation thereof A23B20/00; production, refinement or preservation of animal or vegetable fats or oils C11B, C11C) ## Abstract There is provided a continuous process for fluidizing shortening compositions including a major amount of a normally liquid base oil and a minor amount of a normally solid lipid, the latter exhibiting polymorphic behavior. The composition is flowed through a length of tube and submitted to temperature oscillations alternating between a high temperature which is above the melting point of certain of the crystalline forms of the triglyceride but below that of the desired form (beta), and a low temperature which is below but close to the melting point of the lowest melting crystalline form (alpha). ## Claims ### Claim 1 A process for the continuous fluidization of a feed mixture comprising a major amount of a normally liquid base oil and a minor amount less than about 20% by weight of a normally solid lipid, said normally solid lipid exhibiting polymorphic crystalline behavior and having a beta crystal-forming tendency in said base oil, which process comprises: passing a flow of said feed mixture through a heat exchange zone that is maintained under substantially anaerobic conditions while submitting it to a sequence of at least two temperature oscillations that alternate between (a) a higher temperature which is above the melting temperature of alpha crystals in the solidifying lipid present but below the melting temperature of beta crystals in the solidifying lipid present and (b) a lower temperature which is below the melting temperature of alpha crystals in the solidifying lipid present but sufficiently high to maintain the fluency of the materials in process, continuing said temperature oscillations in said zone until a substantial proportion of said normally solid lipid is transformed into beta crystal form, and withdrawing the resulting composition from said heat exchange zone. ### Claim 2 (depends on 1) A process as defined in claim 1 wherein the feed mixture is nucleated before passing through the heat exchange zone. ### Claim 3 (depends on 2) A process as defined in claim 2 wherein the feed mixture is nucleated by shock cooling. ### Claim 4 A process for the continuous fluidization of a composition including a major amount of a normally liquid base oil and a minor amount less than about 20% by weight of a normally solid lipid, said composition having an overall Iodine Value in the range of from about 75 to about 125 and exhibiting for said normally solid lipid polymorphic crystalline behavior, which process comprises flowing under substantially anaerobic conditions, a body of said composition through a continuous tube and submitting the composition to a sequence of at least two temperature oscillations while in said tube alternating between a high temperature which is above the melting point of the lower melting crystalline forms but below the melting point of the highest melting crystalline form, and a low temperature which is below the melting point of the lowest melting crystalline form, but no more than about 5.degree. F. below, whereby a fluidizing portion of said normally solid lipid is transformed to the highest melting crystalline form and is suspended in said base oil and the resulting composition is stably fluid and pourable at ordinary temperatures. ### Claim 5 (depends on 1) A process as defined in claim 1 wherein no substantial part of said normally liquid base oil melts at a temperature above about 60.degree. F. and no substantial part of said normally solid lipid has a melting point below about 100.degree. F. ### Claim 6 (depends on 1) A process as defined in claim 1 wherein the normally solid lipid includes a normally solid triglyceride. ### Claim 7 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein said normally liquid base oil and said normally solid lipid are edible. ### Claim 8 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the temperature oscillations have an amplitude of from about 8.degree. F. to about 25.degree. F. ### Claim 9 (depends on 4, 5) A process as defined in any of claims 4, 5, or 6 wherein the normally solid lipid in the final product is converted to the highest melting crystalline form to the extent of at least about 80% of the total amount of normally solid lipid initially present. ### Claim 10 (depends on 4, 5) A process as defined in any of claims 4, 5, or 6 wherein the highest melting crystalline form is the beta form. ### Claim 11 (depends on 6) A process as defined in claim 6 wherein the normally solid triglyceride in the final product is converted to the beta form to the extent of at least about 85% of the total amount of normally solid triglyceride initially present. ### Claim 12 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the minimum residence time under flow conditions is in the range of from 1 to about 25 minutes, and the flow rate is from 30 to about 50 pounds per hour. ### Claim 13 (depends on 1, 2, 3, 4, 5, 6) A process as defined in any of claims 1, 2, 3, 4, 5 or 6, wherein the flow is plug flow substantially free of backmixing. ### Claim 14 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the temperature difference between the high temperature and the low temperature in successive cycles increases within the range of amplitudes of from about 8.degree. F. to about 25.degree. F. ### Claim 15 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the normally liquid base oil is partially hydrogenated soybean oil. ### Claim 16 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the normally liquid base oil is a partially hydrogenated vegetable oil. ### Claim 17 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the normally liquid base oil is a mixture of partially hydrogenated vegetable oils. ### Claim 18 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the normally liquid base oil also includes normally liquid mono- and diglycerides carried therein. ### Claim 19 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the high temperature is no more than 117.degree. F. and the low temperature is no less than 65.degree. F., the residence time under flow conditions is from 1 to 25 minutes, the number of temperature cycles is from 3 to 4, and the amplitude of the temperature oscillations is between about 8.degree. F. and 25.degree. F. ### Claim 20 (depends on 3) A process as defined in claim 3 wherein the composition is nucleated by votation. ### Claim 21 (depends on 1, 2, 3) A process as defined in any of claims 1, 2, 3, or 4 wherein the composition is nucleated by votation and the exit temperature from votation is in the range of from 65.degree. F. to 100.degree. F. ### Claim 22 (depends on 1, 2, 3, 4, 5) A process as defined in any of claims 1, 2, 3, 4, 5, or 6 wherein the fluid undergoing the temperature oscillations is mechanically worked.