# US 4,391,786 A · Production of calcium carbide

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- Number: US 4,391,786 A
- Document ID: US4391786A
- Status: Granted
- Kind: A
- Application number: 06/301,836
- Filed: 1981-09-14
- Granted: 1983-07-05
- Earliest claimed: 1980-09-17
- Assignees: Hoechst Aktiengesellschaft
- Inventors: Hans-Joachim Kersting; Erhard Wolfrum; Willi Portz; Georg Strauss
- Web page: https://patentgrep.com/patent/US4391786A

## CPC

- C01B 32/942: Calcium carbide
- Y02P 20/129: Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

The invention relates to a process for making calcium carbide by reacting an excess of coke with quicklime in the presence of oxygen in an oxygen-thermal furnace. To this end, the invention provides for precrushed coal to be used as starting material for coke and precrushed lime hydrate (Ca(OH).sub.2) or precrushed limestone (CaCO.sub.3) to be used as a starting material for quicklime. The precrushed materials are mixed and the resulting mixture is introduced into a drying zone and freed therein at 80.degree. to 120.degree. C. from adhering water. Next, the warm mixture coming from the drying zone, and air, are introduced into a calcining apparatus in which the coal constituent is coked and the lime constituent is simultaneously dehydrated or decarbonized, at temperatures of 900.degree. to 1400.degree. C. The thermally-pretreated mixture of starting materials with an inherent temperature of 900.degree. to 1000.degree. C. is then directly introduced into the oxygen-thermal furnace and reacted with oxygen to calcium carbide.

## Claims

### Claim 1

A process for making calcium carbide by reacting an excess of coke with quicklime in the presence of oxygen in an oxygen-thermal furnace, which comprises: using precrushed coal as a starting material for coke and precrushed lime hydrate (Ca(OH).sub.2) or precrushed limestone (CaCO.sub.3) as a starting material for quicklime; mixing the precrushed materials, introducing the resulting mixture into a drying zone and freeing it therein at 80.degree. to 120.degree. C. from adhering water; introducing the warm mixture coming from the drying zone, and air, into a calcining apparatus, the coal constituent being coked and the lime constituent being simultaneously dehydrated or decarbonized therein at temperatures of 900.degree. to 1400.degree. C.; directly delivering the thermally-pretreated mixture of starting materials with an inherent temperature of 900.degree. to 1000.degree. C. to the oxygen-thermal furnace and reacting it with oxygen to produce calcium carbide therein, using the waste heat originating from the calcining apparatus for the generation of superheated high pressure steam from boiler feed water; using the superheated high pressure steam for operating a turbine, the latter being used for the liquefaction of air and separation into its components at low temperature so as to obtain the oxygen necessary for operation of the oxygen-thermal furnace, and also for the generation of electrical power, hot low pressure steam issuing through the turbine's opposite side being introduced at least partially into the drying zone for drying the mixture of starting materials therein; and taking condensate obtained in the drying zone therefrom, preheating it by means of off-gases originating from the oxygen-thermal furnace, and using it as boiler feed water for the generation of superheated high pressure steam by means of waste heat originating from the calcining apparatus.

### Claim 2 (depends on 1)

A process as claimed in claim 1, wherein a hearth furnace is used as the calcining apparatus.

### Claim 3 (depends on 1)

A process as claimed in claim 1, wherein lignite is used as coal.

### Claim 4 (depends on 1)

A process as claimed in claim 1 wherein said coal constituent consists essentially of moist lignite, and wherein the moist lignite is crusehd to material with a size of up to 10 mm and the crushed material is mixed with lime.

### Claim 5 (depends on 1)

A process as claimed in claim 1, wherein the lime hydrate or limestone is used in the form of material with a size of up to 10 mm.

### Claim 6 (depends on 1)

A process as claimed in claim 1, wherein lime hydrate obtained on reacting the carbide with water to form acetylene is recycled to the carbide production stage as a starting material for making quicklime, and mixed with precrushed coal ahead of the drying zone.