# US 4,391,783 A · Process for making abrasion-resistant sodium tripolyphosphate

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- Number: US 4,391,783 A
- Document ID: US4391783A
- Status: Granted
- Kind: A
- Application number: 06/356,023
- Filed: 1982-03-08
- Granted: 1983-07-05
- Earliest claimed: 1981-03-13
- Assignees: Hoechst Aktiengesellschaft
- Inventors: Hans Haas; Werner Kowalski
- Web page: https://patentgrep.com/patent/US4391783A

## CPC

- C01B 25/412: {Preparation from alkali metal orthophosphates}
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}

## Abstract

The disclosure relates to a process for making granular sodium tripolyphosphate of high abrasion resistance. To this end, the disclosure provides for sodium orthophosphate to be subjected to a one-stage spray-drying operation inside a heated spray tower by means of a nozzle with condensation of the orthophosphate. More particularly the orthophosphate is sprayed jointly with a solution of a high molecular weight phosphate of sodium, potassium or ammonium.

## Claims

### Claim 1

A process for making granular sodium tripolyphosphate of high abrasion resistance which comprises: spray-drying a sodium orthophosphate solution or suspension containing Na.sub.2 O and P.sub.2 O.sub.5 in essentially the molar ratio required for the sodium tripolyphosphate in a one-stage spray-drying operation by means of a nozzle inside a heated spray tower with the resultant formation of the tripolyphosphate, the orthophosphate solution or suspension being sprayed jointly with a solution of a high molecular weight phosphate of sodium, potassium or ammonium containing between 60 and 73 weight % P.sub.2 O.sub.5, the proportion of the said solution being 0.005 to 5 weight %, calculated as solid substance and based on the P.sub.2 O.sub.5 -content of the orthophosphate solution or suspension.

### Claim 2 (depends on 1)

The process as claimed in claim 1, wherein the solution of the high molecular weight phosphate is mixed inside the nozzle with the sodium orthophosphate solution or suspension just prior to spraying.

### Claim 3 (depends on 2)

The process as claimed in claim 2, wherein the solution of the high molecular weight phosphate is mixed with the sodium orthophosphate solution or suspension in such a manner that prior to being sprayed the components remain in contact with each other over a period of less than 0.4 second.

### Claim 4 (depends on 1)

The process as claimed in claim 1, wherein the solution of the high molecular weight phosphate contains 0.5 to 25 weight % of dissolved high molecular weight phosphate.

### Claim 5 (depends on 1)

The process as claimed in claim 1, wherein the high molecular weight phosphate is used in a proportion of 0.01 to 0.1 weight %.

### Claim 6 (depends on 1)

The process as claimed in claim 1, wherein the product is hydrated by treating it with a suitable quantity of water or steam so as to establish a 22.7 weight % content of water of crystallization therein.

### Claim 7

A process for making abrasion-resistant, granular, substantially anhydrous sodium tripolyphosphate which consists essentially of:
mixing a sodium orthophosphate solution or suspension containing Na.sub.2 O and P.sub.2 O.sub.5 in essentially the molar ratio required for the sodium tripolyphosphate with a solution of a high molecular weight phosphate of sodium, potassium or ammonium containing between 60 and 73 weight % P.sub.2 O.sub.5, the proportion of the said solution being 0.005 to 5 weight %, calculated as solid substance and based on the P.sub.2 O.sub.5 -content of the orthophosphate solution or suspension;
spray-drying the resulting mixture in a one-stage spray-drying operation by means of a nozzle inside a heated spray tower;
recovering from the spray tower the abrasion-resistant, granular, substantially anhydrous sodium tripolyphosphate which results from the one-stage spray-drying operation.

### Claim 8 (depends on 7)

A process according to claim 7 wherein the abrasion-resistant, granular, substantially anhydrous sodium tripolyphosphate product recovered from the spray tower is hydrated with water or steam to introduce water of crystallization into said product.