# US 4,391,727 A · Non-caking bleach containing molecular sieve zeolite

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- Number: US 4,391,727 A
- Document ID: US4391727A
- Status: Granted
- Kind: A
- Application number: 06/299,506
- Filed: 1981-09-04
- Granted: 1983-07-05
- Earliest claimed: 1975-12-15
- Assignees: Colgate-Palmolive Company
- Inventors: Claude L. Benz
- Web page: https://patentgrep.com/patent/US4391727A

## CPC

- C11D 3/128: {Aluminium silicates, e.g. zeolites (C11D3/1253 takes precedence)}
- C11D 3/3942: {Inorganic per-compounds (C11D3/3902 takes precedence)}
- C11D: DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL

## Abstract

A non-caking bleaching composition, based on sodium perborate as the active bleaching component, includes certain proportions of sodium perborate tetrahydrate, water soluble inorganic builder salt and an aluminum silicate zeolite. The composition is a free flowing particulate spray dried base admixed with the sodium perborate tetrahydrate and at least part of the zeolite.

## Claims

### Claim 1

A non-caking bleaching composition comprising: by weight from 28.5 to 34.9% sodium perborate tetrahydrate; from 8.1 to 9.9% sodium carbonate; from 8.1 to 9.9% sodium silicate having an Na.sub.2 O:SiO.sub.2 ratio of about 1:2.35; from 0.9 to 1.1% calcined aluminum silicate clay; from 33.9 to 41.3% sodium sulfate; from 8.1% to 9.9% of a crystalline, water-insoluble aluminosilicate molecular sieve 4A zeolite having a particle size of from 5 to 9 microns, and being in about a 2% hydrated form; the composition having a moisture content of about 1.8 to 2.2%.

### Claim 2 (depends on 1)

A composition according to claim 1 comprising about 31.7% sodium perborate tetrahydrate, about 9% sodium carbonate, about 9% sodium silicate, about 1% clay, about 37.6% sodium sulfate, about 9% zeolite, and about 2% moisture.

### Claim 3 (depends on 1)

A composition according to claim 1 comprising spray dried particles of the sodium carbonate, sodium silicate and sodium sulfate in admixture with the sodium perborate tetrahydrate, the clay and the zeolite.
