# US 4,391,612 A · Gasification of coal

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- Number: US 4,391,612 A
- Document ID: US4391612A
- Status: Granted
- Kind: A
- Application number: 06/267,959
- Filed: 1981-05-28
- Granted: 1983-07-05
- Earliest claimed: 1981-05-28
- Assignees: The Halcon SD Group, Inc.
- Inventors: Tsuan Y. Chang
- Web page: https://patentgrep.com/patent/US4391612A

## CPC

- C10J 3/54: Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C10J 3/526: {for entrained flow gasifiers}
- C10J 3/78: High-pressure apparatus
- C10J 2300/093: Coal
- C10J 2300/0943: Coke
- C10J 2300/0946: Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
- C10J 2300/0956: Air or oxygen enriched air
- C10J 2300/0979: as supercritical steam
- C10J 2300/0996: Calcium-containing inorganic materials, e.g. lime
- C10J 2300/1606: Combustion processes
- C10J 2300/1807: Recycle loops, e.g. gas, solids, heating medium, water
- C10J 2300/1846: Partial oxidation, i.e. injection of air or oxygen only
- C10J: PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES (synthesis gas from liquid or gaseous hydrocarbons C01B; underground gasification of minerals E21B43/295); CARBURETTING AIR OR OTHER GASES

## Abstract

A gaseous effluent rich in hydrogen and carbon monoxide is produced from coal by a process which involves the gasification of the coal in a fluidized gasification zone interconnected with a combustor zone comprising a combustion unit and an entrained flow lift column with transfer of solid material between the gasification zone and the combustor zone, in a system in which lime-treated coal and steam are fed to the gasification zone to which heat is supplied by clinker material transferred from the combustor zone. At the same time, gasified coal residue or "char" and clinker are transferred from the gasification zone to the combustor zone wherein the char is brought into contact with air in the presence of the clinker particles circulating from the bottom of the gasification zone, and the final gas and heat values from the coal are extracted by combustion of the char, the coal ash with the lime emerging as fine particles. Heat from the combustion of the char is absorbed by the circulating clinker in the combustion unit and in the lift column of the combustor zone and this heat is transferred to the gasification zone when the clinker is supplied to it. The clinker transferred to the gasification zone, in accordance with the invention, has a predetermined particle size of the order of 1/32 inch to 1/4 inch and represents clinker which is removed from the combustor zone by the action of the rising gases. The thus gas-transported clinker is separated from "fines." The separated clinker particles are transferred to the gasification zone to supply required heat.

## Claims

### Claim 1

A process for the production of a gaseous effluent rich in hydrogen and carbon monoxide from coal which comprises the steps of:
(a) feeding (1) clinker particles and char from the partial gasification with superheated steam of lime-treated coal in a gasification zone, and (2) air to a combustor zone operating at a temperature of 900.degree. C. to 1300.degree. C.;
(b) elevating said clinker particles and any "fines" present by the action of a gaseous stream comprising any excess air and the gases produced by the total combustion of the char with air to a clinker separation zone, said fines comprising ash resulting from the combustion of said char in said combustor zone and lime contained in said coal;
(c) separating the thus-elevated particles and fines in the separation zone into a stream of fines which are suspended in and carried away by the gaseous stream as solid product, and a body of clinker particles deposited from the gaseous stream;
(d) feeding the deposited clinker particles to the upper portion of said gasification zone while feeding lime-treated coal and superheated steam into the lower portion of said gasification zone, the unreacted steam and the gases resulting from the gasification of the lime-treated coal maintaining a fluidized bed comprising said lime-treated coal and the char produced by the partial gasification of the lime-treated coal, with said clinker particles raining down through said fluidized bed as a separate phase, the clinker particles and the steam supplying the heat for the gasification reaction to maintain the fluidized bed at a temperature of 700.degree. C. to 1050.degree. C.;
(e) removing the fuel gas generated in the gasification zone by the partial gasification of the lime-treated coal in the presence of steam, removing the char from the upper portion of the fluidized bed in the gasification zone, removing the clinker particles from the lower portion of the gasification zone;
(f) passing the clinker and char removed from the gasification zone to the combustor zone to provide the feed of char and clinker particles for step (a);
(g) recovering the fines from the gaseous stream of step (c);
(h) preparing clinker particles from at least some of the fines recovered in step (g); and
(i) introducing the clinker particles produced in step (h) to make up for the loss of clinker particles resulting from attrition.

### Claim 2 (depends on 1)

A process as defined in claim 1, wherein the fuel gas removed from said gasification zone is treated to recover entrained char and said recovered char is fed to said combustor zone in step (f).