# US 4,391,611 A · Gasification system

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- Number: US 4,391,611 A
- Document ID: US4391611A
- Status: Granted
- Kind: A
- Application number: 06/240,654
- Filed: 1981-03-05
- Granted: 1983-07-05
- Earliest claimed: 1981-03-05
- Assignees: The United States of America as represented by the United States Department of Energy
- Inventors: Gaurang B. Haldipur; Richard G. Anderson; Peter Cherish
- Web page: https://patentgrep.com/patent/US4391611A

## CPC

- C10J 3/503: {for gasifiers with stationary fluidised bed}
- B01J 8/1827: {the fluidising gas being a reactant}
- C10J 3/482: {Gasifiers with stationary fluidised bed}
- C10J 2200/152: Nozzles or lances for introducing gas, liquids or suspensions
- Y10S 48/04: Powdered fuel injection
- C10J: PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES (synthesis gas from liquid or gaseous hydrocarbons C01B; underground gasification of minerals E21B43/295); CARBURETTING AIR OR OTHER GASES
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

## Claims

### Claim 1

A method of operating a gasification reactor of the type wherein solid particulate carbonaceous material, oxygen, steam and an oxygen lean medium are fed from an injection means having an upper tip into a vertically disposed vessel housing a combusting fluidized bed to produce a combustible product gas and ash, to prevent substantial sintering of said tip, comprising:
injecting a mixture of said particulate material and a transport gas vertically upward into said fluidized bed at a velocity of between 30 and 70 feet per second;
injecting a mixture of oxygen and steam upwardly into said bed and about the radial periphery of said particulate and gas mixture at a velocity of between 50 and 300 feet per second;
injecting an oxygen lean gaseous medium upwardly into said bed and about the radial periphery of said oxygen and steam mixture at a velocity equal to or less than said oxygen and steam mixture velocity.

### Claim 2 (depends on 1)

The method of claim 1 wherein said particulate and transport gas mixture and said oxygen and steam mixture are injected by said injection means into said fluidized bed at approximately the same elevation, and said oxygen lean gaseous medium is injected upwardly into said fluidized bed at a slightly lower elevation such that said oxygen lean medium sweeps upwardly across said tip.

### Claim 3 (depends on 2)

The method of claim 2 wherein said oxygen lean gaseous medium is injected at an elevation approximately one-half inch below said particulate and transport gas and said oxygen and steam mixture injections.

### Claim 4 (depends on 1)

The method of claim 1 wherein said oxygen and steam mixture is injected upwardly into said bed at an outward angle, said angle being less than 71/2.degree. with respect to vertical.

### Claim 5 (depends on 1)

The method of claim 1 wherein said oxygen lean gaseous medium is injected into said bed in a pulsating fashion.

### Claim 6 (depends on 1)

The method of claim 1 wherein said particulate and transport gas mixture is injected at a velocity greater than the choking velocity of said particulates, said oxygen and steam mixture is injected at a velocity greater than the injection velocity of said particulate and transport mixture, and said oxygen lean gaseous medium is injected at a velocity between approximately 70% and 85% of the injection velocity of said oxygen and steam mixture.

### Claim 7 (depends on 6)

The method of claim 6 wherein said particulate and transport gas mixture injection velocity is between approximately 40 and 60 feet per second, said oxygen and steam mixture injection velocity is greater than 70 feet per second, and said oxygen lean gaseous medium injection velocity is greater than 100 feet per second.

### Claim 8 (depends on 1)

The method of claim 1 wherein said mixture of oxygen and steam are injected at an oxygen concentration greater than 70% by volume.

### Claim 9

A method of operating a gasification reactor of the type wherein solid particulate carbonaceous material, oxygen, steam and an oxygen lean medium are fed from an injection means comprising an upper tip, and a number of vertical concentric tubes into a vertically disposed vessel housing a combusting fluidized bed to produce a combustible product gas and ash, to prevent substantial sintering of said tip, comprising:
injecting a mixture of said particulate material and a transport gas vertically upwardly and into said fluidized bed through a first vertical tube extending upwardly into said bed at a velocity of between 30 and 70 feet per second;
injecting a mixture of oxygen and steam vertically upward and into said fluidized bed through an inner annulus formed between said first vertical tube and a second vertical tube which is concentric with and spaced about, said first vertical tube at a velocity of between 50 and 300 feet per second;
injecting an oxygen lean gaseous medium vertically upwardly and into said fluidized bed through a second annulus formed between said second tube and a third vertical tube which is concentric with, and spaced about, said second vertical tube at a velocity equal to or less than said oxygen and steam mixture velocity.

### Claim 10 (depends on 9)

The method of claim 9 wherein said injecting of particulate material and a transport gas, and said injecting of a mixture of oxygen and steam by said injection means are at a common elevation, and said injecting of an oxygen lean gaseous medium is at an elevation approximately one-half inch below said common elevation such that said oxygen lean medium sweeps upwardly across said tip.