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US 4,388,448 AGranted
Glycidyl methacrylate polymers, their preparation and solvolysis products
AssigneeE. I. Du Pont de Nemours and Company
InventorLester R. Melby
Life of this patent
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Abstract
Homopolymers of glycidyl methacrylate (GMA) and copolymers of GMA with other methacrylate comonomers; their preparation employing an anionic initiator which is the adduct of a selected organo(alkali metal) compound and at least one mole of methyl methacrylate or another lower alkyl methacrylate; as well as solvolyzed forms of the GMA polymers.
Claims10
A polymer selected from the group consisting essentially of:
- (i) poly(glycidyl methacrylate), and
- (ii) copolymer of glycidyl methacrylate and at least one other methacrylate ester capable of anionic polymerization,
- each of said polymer (i) and copolymer (ii) characterized by having
- (a) a polydispersity index (M.sub.w /M.sub.n) between about 1.0 to 1.4, and
- (b) substantially all glycidyl methacrylate epoxide functions intact;
- polymer (i) and copolymer (ii) being represented by the formula
- A--AMA).sub.x (GMA).sub.y (RMA).sub.z Q
- wherein
- A is the organic moiety of an organo(alkali metal) compound used to form an initiator adduct with AMA, said organo(alkali metal) compound being selected from the group consisting essentially of 1,1 diphenylhexyl(alkali metal), adduct of an alkyl(alkali metal) with 1,1-diaryl-substituted ethylene wherein the aryl substituents are free of electrophilic substituents, diisopropylamido(alkali metal), adduct of a secondary or tertiary alkyl(alkali metal) with a pyridine unsubstituted in the 2,5 and 6 positions wherein adduct substituents are nonelectrophilic, cumyl and cumyl-type alkali metal derivatives free of electrophilic substituents, and polynuclear hydrocarbon-alkali metal adducts;
- AMA is alkyl methacrylate in which the alkyl group has 1 to 18 carbon atoms;
- GMA is glycidyl methacrylate;
- RMA represents one or more methacrylate esters selected from the group consisting essentially of alkyl of 1 to 18 carbon atoms, alkenyl of 2 to 18 carbon atoms, alkadienyl of 5 to 18 carbon atoms, dialkylaminoalkyl of about 4 to 12 carbon atoms, alkoxyalkyl of about 3 to 12 carbon atoms, and lower fluoroalkyl;
- x is the number of methacrylate units in the initiator adduct and is at least 1;
- y is the total number of combined GMA units in the chain, and is at least 1 when z is greater than zero, and at least 6 when x is 1 to 3 and z is zero;
- z is the total number of combined RMA units in the chain and is zero in a homopolymer and greater than zero in a copolymer;
- and
- Q is a terminating group formed by terminating the polymerization with a protic material or by warming to room temperature.
14 more elements
Dependencies are inferred from the claim text.