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US 4,385,158 AGranted
Organopolysiloxane composition
AssigneeToray Silicone Company, Ltd.
InventorsRyuzo Mikami, Yuji Hamada
Life of this patent
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Abstract
What is disclosed herein is a room temperature curable, one component epoxy resin modified silicone resin which has excellent heat resistance, adhesiveness to substrates, and is hard. The improvements in properaties are obtained by the use of epoxy fatty acid esters in the coating formulation.
Claims5
An organopolysiloxane composition consisting of
- (A) a curable organopolysiloxane resin composition consisting of
- (1) 100 parts by weight of an organopolysiloxane resin having the unit formula
- R.sub.a SiX.sub.b O.sub.(4-a-b)/2
- wherein R is a substituted or unsubstituted monovalent hydrocarbon radical of 1-18 carbon atoms;
- X is a hydroxyl radical or an alkoxy radical wherein the number of carbon atoms in the alkoxy radical is 1 or 2, a has an average value of 0.9-1.8 and b has an average value of greater than 0 to 1;
- (2) 1-150 parts by weight, based on 100 parts by weight of (1), of an alkoxysilane having the general formula
- R'.sub.m Si(OR").sub.4-m
- wherein R' is a monovalent hydrocarbon radical having 1-6 carbon atoms, R" is an alkyl radical having 1-3 carbon atoms and the value of m is 0, 1 or 2;
- (3) 0.1 to 30 parts by weight, based on 100 parts by weight of (1), of an aminoalkylalkoxysilane having the general formula ##STR2## wherein R"' is hydrogen or the methyl radical, R.sup.iv is a divalent organic radical selected from the group consisting of alkylene groups of 1-3 carbon atoms, the phenylene group, --CH.sub.2 CH.sub.2 C.sub.6 H.sub.4 --, --(CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2), --(NHCH.sub.2 CH.sub.2 CH.sub.2).sub.y and --(NHCH.sub.2 CH.sub.2).sub.y wherein y has a value of 1-3;
- R.sup.v is a monovalent hydrocarbon radical;
- R.sup.vi is an alkyl radical of 1-3 carbon atoms and n has a value of 0 or 1;
- and
- (B) an epoxy resin fatty acid ester.
10 more elements
Dependencies are inferred from the claim text.