Aldehyde-ethers
AssigneeDavy McKee (Oil & Chemicals) Limited
InventorsNorman Harris, Alan J. Dennis, George E. Harrison
Life of this patent
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AssigneeDavy McKee (Oil & Chemicals) Limited
InventorsNorman Harris, Alan J. Dennis, George E. Harrison
Estimating the term…
Aldehyde ethers of the general formula ##STR1## wherein R.sub.1 and R.sub.2 each, independently of the other, represent a C.sub.1 to C.sub.4 alkyl radical, and R.sub.3 and R.sub.4 each, independently of the other, represent a hydrogen atom or a C.sub.1 to C.sub.3 alkyl radical, or wherein R.sub.1 represents a C.sub.1 to C.sub.4 alkyl radical, R.sub.2 and R.sub.3 together with the carbon atoms to which they are attached form a 5-membered or 6-membered cycloaliphatic ring, and R.sub.4 represents a hydrogen atom or a C.sub.1 to C.sub.3 alkyl radical, and wherein Y represents --CH.sub.2 --CH.sub.2 --C.sub.2 or --CH.sub.2 --CH (CH.sub.3)--, are prepared by hydroformylation of a corresponding compound of formula: ##STR2## by reaction with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst, e.g. a rhodium complex catalyst. Preferred compounds include 4-t-butoxybutyraldehyde and 3-t-butoxy-2-methylpropionaldehyde. The compounds are useful chemical intermediates in the production of, for example, butane-1,4-diol, butyrolactone and tetrahydrofuran.
Aldehyde-ethers of the general formula:
4-t-butoxybutyraldehyde.
3-t-butoxy-2-methylpropionaldehyde.
An aldehyde-ether of the formula:
Dependencies are inferred from the claim text.