US 4,383,094 AGranted

Continuous reaction/separation method for solution polymerization of olefins

AssigneeMobil Oil Corporation

InventorsDarrell D. Whitehurst, Tsoung Y. Yan

Life of this patent

Estimating the term…

Loading patent…

Abstract

A solid product resulting from the nucleated growth of the product on solid material of either the same or different composition and having a density higher than the reaction medium is formed from one or more liquid phase reactants by a method which comprises tangentially introducing the liquid phase reaction medium into the lower, smaller end of an inverted, frusto-conical reactor-separator, thereby imparting an upward swirling motion to the reaction medium in the reactor-separator, the horizontal velocity at the bottom of the reactor-separator being sufficiently large to cause fluidization of larger, solid product particles and concentration of them in the central lower portion of the reactor-separator and the vertical velocity at the top of the reactor-separator being sufficiently small to avoid carry-over of the smaller solid particles but sufficiently large to concentrate them in the upper portion of the reactor-separator; at least periodically recovering the larger, solid product particles in spherical form from the bottom of the reactor-separator; and recovering fluid products from the top of the reactor-separator. The method described is useful in a variety of reactions wherein a solid product forms by a nucleated growth mechanism. Examples of such reactions include thermal upgrading of petroleum derived feedstocks and coal liquids, synthesis of zeolites and Ziegler-Natta polymerization of olefins.

Claims9

Dependent claims

A continuous reaction/separation method for solution polymerization of olefins over Ziegler catalysts which comprises:

(a) tangentially introducing solvent, monomer and Ziegler catalysts into the lower, smaller end of an elongated, vertical reaction zone of inverted frusto-conical configuration, thereby imparting an upward, swirling motion to the reaction medium in the reaction zone, the horizontal velocity at the bottom of the reaction zone being sufficient to cause fluidization of larger solid polymer particles and concentration of them in the central, lower portion of the reaction zone and the vertical velocity at the top of the reaction zone being sufficiently small to avoid carry-over of smaller solid polymer particles but sufficiently large to concentrate them in the upper portion of the reaction zone;
(b) maintaining the resulting reaction medium in the reaction zone in a swirling, fluidized state under conditions which promote the formation and growth of solid particles of polymer in solution;
(c) withdrawing a stream comprising gaseous olefins from the top of the reaction zone and returning said gaseous olefins to the reaction zone;
(d) withdrawing a stream comprising substantially solids-free solvent from the upper part of the reaction zone and returning the solvent to the reaction zone;
(e) withdrawing a slurry consisting essentially of larger polymer particles and solvent from the bottom of the reaction zone;
and
(f) recovering solid polymer products from the slurry.

4 more elements

Dependencies are inferred from the claim text.

Facts

Application: 06/296,765Filed 27 Aug 1981 · division
Priority: 6 Aug 1979
Granted: 10 May 1983
Term ends: Not estimatedThe source records don’t support an estimate.

Classification14 codes

C10G 9/005
Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils: coking
B01J 8/20
With fluidised particles: with liquid as a fluidising medium
C01B 39/04
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction…:…
C08F 10/00
Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double