Organophilic clay gellants
AssigneeVenture Innovations, Inc.
InventorRoy F. House
Life of this patent
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Abstract
The invention provides methods of preparing organophilic clays having enhanced dispersibility in organic liquids, the organophilic clay containing gellants, and methods of increasing the viscosity of organic liquids utilizing these gellants.
Claims38
A gellant comprising from about 58% to about 80% of an organophilic clay, from about 3% to about 10% of an alcohol having from 1 to 5 carbon atoms, and from about 15% to about 40% water.
An organoclay gellant slurry containing from about 20% to about 40% of an organophilic clay, from about 24% to about 78% water, and from about 2% to about 48% of an alcohol having from 1 to 5 carbon atoms, wherein the water to alcohol ratio is in the range from about 97.5/2.5 to about 35/65.
The method of producing an organoclay gellant which comprises extruding a mixture containing a smectite clay, from about 75 to about 120 milliequivalents per 100 grams of 100% active clay of a quaternary compound selected from the group consisting of quaternary ammonium salts, quaternary phosphonium salts, and mixtures thereof, from about 25% to about 100%, based on the weight of 100% active clay, of water, and from about 5% to about 30%, based on the weight of 100% active clay, of an alcohol containing from 1 to 5 carbon atoms, and thereafter grinding the organoclay gellant without removing the water or alcohol therefrom.
The method of producing an organoclay gellant slurry which comprises extruding a mixture containing a smectite clay, from about 75 to about 120 milliequivalents per 100 grams of 100% active clay of a quaternary compound selected from the group consisting of quaternary ammonium salts, quaternary phosphonium salts, and mixtures thereof, from about 20% to about 100%, based on the weight of 100% active clay, of water, and from about 5% to about 50%, based on the weight of 100% active clay, of an alcohol containing from 1 to 5 carbon atoms, and thereafter shearing the extruded organoclay gellant in sufficient water and alcohol to produce said slurry, said slurry containing from about 20% to about 40% organoclay, from about 24% to about 78% water, and from about 2% to about 48% of said alcohol, wherein the water to alcohol ratio is in the range from about 97.5/2.5 to about 35/65.
A method of increasing the viscosity of an oleaginous liquid which comprises extruding a mixture containing a smectite clay, from about 80 to about 110 milliequivalents per 100 grams of 100% active clay of a quaternary compound selected from the group consisting of quaternary ammonium salts, quaternary phosphonium salts, and mixtures thereof, from about 35% to about 100%, based on the weight of 100% active clay, of water, and from about 5% to about 30%, based on the weight of 100% active clay, of an alcohol containing from 1 to 5 carbon atoms, and thereafter dispersing the extrudate into the oleaginous liquid without removing the water of alcohol therefrom.
A method of increasing the viscosity of an oleaginous liquid which comprises extruding a mixture containing a smectite clay, from about 80 to about 110 milliequivalents per 100 grams of 100% active clay of a quaternary compound selected from the group consisting of quaternary ammonium salts, quaternary phosphonium salts, and mixtures thereof, from about 20% to about 100%, based on the weight of 100% active clay, of water, and from about 5% to about 50%, based on the weight of 100% active clay, of an alcohol containing from 1 to 5 carbon atoms, shearing the extrudate in sufficient water and said alcohol to produce a slurry, said slurry containing from about 20% to about 40% organoclay, from about 24% to about 78% water, and from about 2% to about 48% of said alcohol, wherein the water to alcohol ratio is in the range from about 97.5/2.5, to about 35/65, and thereafter mixing said slurry with said oleaginous liquid.
Dependencies are inferred from the claim text.