Process and apparatus for continuous production of polyesters
AssigneeDidier Engineering GmbH
InventorsFriedhelm Kapteina, Jurgen Rink
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AssigneeDidier Engineering GmbH
InventorsFriedhelm Kapteina, Jurgen Rink
Estimating the term…
Process and apparatus for continuous production of polyesters, characterized by an improvement in the esterification or interesterification stage, in which a mixture containing the starting materials, for example, terephthalic acid and ethylene glycol, is subjected to the shearing and homogenizing action of a rotor-stator, and the resultant homogeneous mixture is introduced into a thin-layer evaporator to produce a reaction mixture containing low molecular weight bis-hydroxyalkylene ester. This lower molecular weight product is then subjected to precondensation and polycondensation in accordance with conventional procedures to obtained the desired polyester product. In accordance with the present invention, the esterification degree can be increased substantially, without deteriorating the quality of the polyester.
In a process for continuous production of a polyester which comprises reacting (A) normally solid terephthalic acid with (B) normally liquid ethylene glycol, to produce a low molecular weight bis-.beta.-hydroxyethylene terephthalate, subjecting said bis-.beta.-hydroxyethylene terephthalate to precondensation under reduced pressure to produce an intermediate ethylene terephthalate product of increased molecular weight, and subjecting said intermediate product of polycondensation under further reduced pressure to increase the molecular weight of the intermediate product and thus produce polyethylene terephthalate, the improvement which comprises
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