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US 4,382,131 AGranted
Thermoplastic block copolyesters, a process for their production and their use for the production of mouldings
AssigneeBayer Aktiengesellschaft
InventorsRudolf Binsack, Karl-Heinz Kohler, Leo Morbitzer, Ludwig Bottenbruch, Walter Heitz
Life of this patent
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Abstract
Block copolyesters based on polyalkylene terephthalates which contain polyene blocks show an extremely low deformation even when they are processed into thin articles. They still have a crystallinity which is decreased by less than the ratio corresponding to the polyene portion.
Claims10
Block copolyesters having a relative viscosity (as measured in phenol/o-dichlorobenzene, ratio by weight 1:1--at 25.degree. C.) of from 1.15 to 3.0 and, disregarding the terminal groups, consisting of:
- (A) from 1 to 60% by weight, based on the block copolyester, a long-chain units corresponding to the following formula ##STR7## and/or ##STR8## and/or ##STR9## and (B) from 40 to 99% by weight, based on the block copolyester, of short-chain units corresponding to the following formula ##STR10## characterised in that M is a difunctional polymethylene radical containing terminal bonding sites and having an average molecular weight M.sub.n of from 400 to 5000;
- any side chains present must be methyl and/or ethyl groups and the polydiene radical on which the polymethylene residue is based contains at least 50 mole percent of 1,4-bonds,
- G is a difunctional aliphatic radical containing from 1 to 12 carbon atoms and/or a difunctional cycloaliphatic radical containing from 6 to 12 carbon atoms and having a molecular weight below 300, at least 70 mole percent of G consisting of one and the same radical,
- X is a direct bond or a difunctional aliphatic, cycloaliphatic and/or aromatic radical containing from 1 to 14 carbon atoms and having a molecular weight below 300, at least 70 mole percent of X consisting of 1,4-phenylene radicals.
1 more element
Dependencies are inferred from the claim text.