Uranium extraction process
AssigneeAlbright & Wilson Limited
InventorMark A. Rose
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Abstract
Uranium is extracted from wet process phosphoric acid by extraction with a mixture of a diorganophosphate and a neutral phosphorus compound, which is preferably a triorgano phosphine oxide, in the presence of nitrate to form an organic extract layer containing uranium and an aqueous acid layer, which are separated.
Claims19
A process for extracting uranium from a wet process phosphoric acid containing uranium, which process comprises contacting said phosphoric acid, which contains 35-60% by weight of P.sub.2 O.sub.5 and uranium at least some of which is in the hexavalent state, with a solution in an inert non polar water immiscible organic solvent of a neutral phosphorus compound of formula ##STR3## where each of a, b and c, which are the same or different, is 0 or 1, and each of R.sup.1, R.sup.2 and R.sup.3, which are the same or different, is an alkyl, cycloalkyl or alkenyl group, and an acid ester of formula (R.sup.4 O).sub.2 PO(OH), where R.sup.4 is as defined for R.sup.1 -R.sup.3, and wherein said phosphoric acid containing uranium contains nitrate ion in an amount between 0.05 and 10% to form an organic extract phase containing uranium and an aqueous phosphoric acid, which are separated.
Dependencies are inferred from the claim text.