# US 4,382,002 A · Drilling fluids containing an additive composition

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- Number: US 4,382,002 A
- Document ID: US4382002A
- Status: Granted
- Kind: A
- Application number: 06/277,053
- Filed: 1981-06-24
- Granted: 1983-05-03
- Earliest claimed: 1981-06-24
- Assignees: Exxon Research & Engineering Co.
- Inventors: Thad O. Walker; Darrell W. Brownawell; Antonio Gutierrez
- Web page: https://patentgrep.com/patent/US4382002A

## CPC

- C09K 8/22: Synthetic organic compounds
- C07C 323/00: Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS

## Abstract

Aqueous drilling fluids containing a minor amount of an additive composition featuring mono- and di-esters of C.sub.12 -C.sub.50 aliphatic hydrocarbon substituted succinic acids or anhydrides, such as octadecenyl succinic anhydride with thio-bis-alkanols such as dithiodiethanol. Such fluids are especially useful where reduced torque drilling fluids are needed. Another embodiment of this invention relates to a method of drilling utilizing the above-described fluids.

## Claims

### Claim 1

An alkaline drilling mud comprising particles of clayey material suspended in sufficient water to render it circulatable and an effective amount of an ester compound formed by the reaction of:
(a) a thio-bis-alkanol of the formula: ##STR4## wherein R and R' each independently may be hydrogen, methyl or ethyl, x may be 1-4, y may be 0, 1 or 2, a, b, c, and d, each independently maybe 1-3; with (b) 1 to 2 moles, per mole of the thio-bis-alkanol, of an aliphatic hydrocarbon substituted succinic acid or anhydride wherein the aliphatic hydrocarbon group contains from about 12 to 50 carbon atoms whereby the drilling torque of said mud is reduced.

### Claim 2 (depends on 1)

A mud according to claim 1 wherein said ester compound is the mono-ester of dithiodiethanol with octadecenyl succinic anhydride.

### Claim 3 (depends on 1)

A mud according to claim 1 wherein said ester compound the di-ester of dithiodiethanol with octadecenyl succinic anhydride.

### Claim 4

In a process for drilling a well with well drilling tools wherein there is circulated in the well an alkaline drilling mud containing particles of clayey material suspended in sufficient water to render the same circulatable, the method of reducing the drilling torque of the drilling mud comprising adding to each barrel of said mud from 0.1 to 10 pounds of an ester compound formed by the reaction of:
(a) a thio-bis-alkanol of the formula: ##STR5## wherein R and R' each independently may be hydrogen, methyl or ethyl, x may be 1-4, y may be 0, 1 or 2, a, b, c, and d, each independently maybe 1-3; with (b) 1 to 2 moles, per mole of the thio-bis-alkanol, of an aliphatic hydrocarbon substituted succinic acid or anhydride wherein the aliphatic hydrocarbonyl group contains from about 12 to 50 carbon atoms whereby the drilling torque of said mud is reduced.

### Claim 5

An additive combination for increasing the lubricity of drilling muds consisting essentially of from 30 to 70 parts by weight of an ester compound dissolved in a hydrocarbon solvent, said ester compound being formed by the reaction of:
(a) a thio-bis-alkanol of the formula: ##STR6## wherein R and R' each independently may be hydrogen, methyl or ethyl, x may be 1-4, y may be 0, 1 or 2, a, b, c, and d, each independently maybe 1-3; with (b) 1 to 2 moles, per mole of the thio-bis-alkanol, of an aliphatic hydrocarbon substituted succinic acid or anhydride wherein the aliphatic hydrocarbon group contains from about 12 to 50 carbon atoms whereby the drilling torque of said mud is reduced.