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US 4,381,418 AGranted
Catalytic dehydrogenation process
AssigneeUop LLC
InventorsSteve A. Gewartowski, Dennis E. O'Brien
Life of this patent
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Abstract
A process for the catalytic dehydrogenation of C.sub.2 + normally gaseous paraffinic hydrocarbons to produce the corresponding monoolefinic hydrocarbons is disclosed. The energy-efficient process is particularly directed to the separation of recycle hydrogen from the olefinic hydrocarbon products and unreacted paraffinic hydrocarbons.
Claims9
A catalytic dehydrogenation process which comprises the steps of:
- (a) heat exchanging a C.sub.2 + normally gaseous paraffinic hydrocarbon feed stream with a net hydrogen product stream and a net hydrocarbon product stream chilled in accordance with step (g);
- (b) further cooling said hydrocarbon feed stream by admixture with a hydrogen recycle stream chilled in accordance with step (g) and recycled in accordance with step (h);
- (c) heating the combined hydrogen/hydrocarbon stream by indirect heat exchange with a reaction zone effluent stream compressed in accordance with step (e);
- (d) contacting the heated combined stream with a dehydrogenation catalyst in a reaction zone at dehydrogenation conditions producing a reaction zone effluent stream comprising hydrogen, olefinic hydrocarbon product and unreacted paraffinic hydrocarbons;
- (e) compressing said effluent stream and cooling the same by indirect heat exchange with the combined stream in accordance with step (c) and forming a liquid hydrocarbon phase and a hydrogen-rich vapor phase;
- (f) separating the thus cooled liquid hydrocarbon phase;
- (g) expanding the hydrogen-rich vapor phase to effect a further chilling and condensation of a residual hydrocarbon phase therefrom;
- (h) combining one portion of the chilled vapor phase with the hydrocarbon feed stream as recycle hydrogen in accordance with step (b);
- (i) heat exchanging the remaining portion of the chilled hydrogen-rich vapor phase with the hydrocarbon feed stream in accordance with step (a) and thereafter recovering said vapor phase as a net hydrogen product stream;
- (j) combining the cooled liquid hydrocarbon phase from step (f) and the chilled residual hydrocarbon phase from step (g), heat exchanging the combined hydrocarbon stream with the hydrocarbon feed stream in accordance with step (a), and thereafter recovering the combined stream as a net hydrocarbon products stream comprising olefinic hydrocarbon products stream comprising olefinic hydrocarbon products and unreacted paraffinic hydrocarbons.
7 more elements
Dependencies are inferred from the claim text.