# US 4,381,353 A · Sprayed polyurethane foams employing reactive amines to improve the foam surface

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- Number: US 4,381,353 A
- Document ID: US4381353A
- Status: Granted
- Kind: A
- Application number: 06/317,708
- Filed: 1981-11-02
- Granted: 1983-04-26
- Earliest claimed: 1981-11-02
- Assignees: Texaco Inc.
- Inventors: Kenneth G. McDaniel
- Web page: https://patentgrep.com/patent/US4381353A

## CPC

- C08G 18/6614: {with compounds of group C08G18/3225 or C08G18/3271 and/or polyamines of C08G18/38}
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

## Abstract

A polyurethane foam formulation for use primarily in sprayed applications has been discovered which provides a smoother than average foam surface. The formulation includes the addition of a primary or secondary mono or polyamine having a hydrogen functionality of two or greater. The compressive strengths of the resultant foams are equivalent to or greater than equivalent formulations without the amines, even though the amines also reduce fluorocarbon loss yielding lower density foams.

## Claims

### Claim 1

A rigid polyurethane foam formulation suitable for spray application comprising
a. a polyether or polyester polyol,
b. an organic polyisocyanate,
c. a halocarbon blowing agent,
d. a catalytic amount of a urethane catalyst and
e. 1 to 4 weight percent of an alkanolamine surface-improving additive where the alkanolamine additive is diethanolamine.

### Claim 2

A rigid polyurethane foam formulation suitable for spray application comprising
a. a polyether or polyester polyol,
b. an organic polyisocyanate,
c. a halocarbon blowing agent,
d. a catalytic amount of a urethane catalyst and
e. 1 to 4 weight percent of an alkanolamine surface-improving additive where the alkanolamine additive is 2-(2-aminoethoxy)ethanol.

### Claim 3 (depends on 1)

The rigid polyurethane foam formulation of claim 1 in which the polyol is prepared by reacting from 2 to 3 moles of propylene oxide with one mole of the Mannich reaction product of a mole of phenol or nonylphenol with one or two moles of formaldehyde and one or two moles of diethanolamine.

### Claim 4 (depends on 1)

The rigid polyurethane foam formulation of claim 1 in which the halocarbon blowing agent is trichlorofluoromethane.

### Claim 5

A cured rigid polyurethane foam having a smooth surface being produced by the process of spraying a polyurethane foam formulation comprising
a. a polyether or polyester polyol,
b. an organic polyisocyanate,
c. a halocarbon blowing agent,
d. a catalytic amount of a urethane catalyst and
e. 1 to 4 weight percent of an alkanolamine surface-improving additive being selected from the group of alkanolamines consisting of 2-(2-aminoethoxy)ethanol and diethanolamine.

### Claim 6

An improved method for producing a rigid polyurethane foam having a smooth surface comprising spraying a polyurethane foam formulation comprising
a. a polyether or polyester polyol,
b. an organic polyisocyanate,
c. a halocarbon blowing agent,
d. a catalytic amount of a urethane catalyst and
e. the improvement comprising the inclusion of 1 to 4 weight percent of an alkanolamine surface-improving additive being selected from the group of alkanolamines consisting of 2-(2-aminoethoxy)ethanol and diethanolamine.