# US 4,379,727 A · Method of laser annealing of subsurface ion implanted regions

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- Number: US 4,379,727 A
- Document ID: US4379727A
- Status: Granted
- Kind: A
- Application number: 06/281,267
- Filed: 1981-07-08
- Granted: 1983-04-12
- Earliest claimed: 1981-07-08
- Assignees: International Business Machines Corporation
- Inventors: Howard H. Hansen; Jerome B. Lasky; Ronald R. Silverman
- Web page: https://patentgrep.com/patent/US4379727A

## CPC

- H10W 15/00: Highly-doped buried regions of integrated devices
- H10P 34/42: with electromagnetic radiation, e.g. laser annealing (laser cutting H10P54/20)
- H10W 15/01: {Manufacture or treatment}
- Y10S 148/092: Laser beam processing-diodes or transistor
- Y10S 148/093: Laser beam treatment in general
- H10W: GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

A method for annealing ion implanted regions buried in a semiconductor substrate without the undesirable effects of thermal diffusion which includes the radiation of the substrate by a continuous laser having an emission frequency longer than 600 nanometers which the buried ion implanted regions will absorb strongly but which will be substantially unabsorbed by the unimplanted regions. Superior results can be obtained when the substrate is heated to approximately 300.degree. during this laser annealing.

## Claims

### Claim 1

A method of annealing buried ion implanted regions in a semiconductor body comprising;
ion implanting impurity ions into a crystalline semiconductor body to provide in the body a buried region having a high concentration of said impurity ions at a predetermined depth below the surface, and
annealing said buried region by exposure of the body to the emission of a continuous wave laser having an emission frequency which is substantially absorbed by the buried region and to which the remainder of the body is substantially transparent to cause electrical activation of the implanted ions in said buried region without substantial thermal diffusion of the implanted species.

### Claim 2 (depends on 1)

The method of claim 1 wherein there is further provided the step of heating the body to approximately 300+ C. during exposure of the body to said laser to eliminate the effect of any instability in the laser beam and prevent damage to said body.

### Claim 3 (depends on 1)

The method of claim 1 wherein said body comprises silicon and said implanted ions are phosphorous ions implanted at an energy level of 400 keV with a dosage of 1 to 5.times.10.sup.15 centimeter.sup.2.

### Claim 4 (depends on 2)

The method of claim 2 wherein said emission frequency of said laser is larger than 600 nanometers.

### Claim 5 (depends on 1)

The method of claim 1 wherein said laser is a Yittrium Aluminum Garnet continuous wave laser operating at a wavelength of 1.06 microns.

### Claim 6 (depends on 4)

The method of claim 4 wherein said buried region lies between 0.5 microns and 5.0 microns below the surface of a body and the peak concentration of implanted ions in said body ranges from 10.sup.15 to 10.sup.20 ions per centimeter.sup.3.

### Claim 7 (depends on 2)

The method of claim 2 wherein there is further provided after said annealing step the steps of ion implanting a base region and an emitter region in said buried region.

### Claim 8

A method of annealing buried ion implantated regions in a semiconductor body without undesirable effects of thermal diffusion of said implanted region by a continuous laser having an emission frequency at which said ion implanted regions absorb strongly and at which the unimplanted regions are substantially unabsorbed to cause electrical activation of the implanted ions in said region without substantial thermal diffusion of the implanted ions and heating the body to approximately 300.degree. C. during exposure of the body to said laser to eliminate the effects of any instability in said laser.

### Claim 9

A method of forming and annealing deep buried ion implanted regions in a semiconductor body comprising;
ion implanting impurity ions into a crystalline semiconductor body to provide a buried region having its highest concentration of impurity ions at a predetermined depth of at least 0.35 microns below the surface of the body, and
annealing the buried region by exposure of said body to the light emitted by a continuous wave laser having an emission frequency greater than 600 nanometers to which the unimplanted body is substantially transparent but which is substantially absorbed by the buried region.