# US 4,379,036 A · Continuous electrochemical ammonia scrubber

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- Number: US 4,379,036 A
- Document ID: US4379036A
- Status: Granted
- Kind: A
- Application number: 06/291,138
- Filed: 1981-08-07
- Granted: 1983-04-05
- Earliest claimed: 1981-08-07
- Assignees: United Technologies Corporation
- Inventors: Harold R. Kunz; Paul J. Damiano; Francis J. Luczak
- Web page: https://patentgrep.com/patent/US4379036A

## CPC

- H01M 8/0662: Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- B01D 53/326: {in electrochemical cells}
- B01D 53/58: Ammonia
- Y02A 50/20: Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- Y02A: TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A continuous process of removing ammonia gas from a gas stream is disclosed. A bed of solid porous material is provided which is wetted with an acid and the ammonia gas is removed by reacting with the acid to form an ammoniated salt. The porous material containing the acid is held at an electrochemical potential sufficient to oxidize the ammoniated salt of the acid to produce nitrogen gas regardless of the content of the gas stream. The porous substrate can be flooded with an insulating layer to permit entry of only the formed salt and a barrier to the, for example, reducing gas, thereby improving the efficiency of the system.

## Claims

### Claim 1

In the continuous removal of ammonia gas from a gas stream, the steps of providing a bed of solid porous material wetted with an acid, removing ammonia gas from the gas stream by reacting ammonia in the gas stream with the acid to form an ammoniated salt of the acid on said porous material, and continuously converting the ammoniated salt to acid, nitrogen gas and hydrogen gas by holding the porous material at an electrochemical potential sufficient to oxidize the ammoniated salt of the acid.

### Claim 2 (depends on 1)

The process of claim 1 wherein the gas stream is hydrogen.

### Claim 3 (depends on 1)

The process of claim 1 wherein the potential is about 0.7 to about 1.0 volt.

### Claim 4 (depends on 1)

The process of claim 1 wherein the acid is phosphoric acid and the salt is ammonium dihydrogen phosphate.

### Claim 5 (depends on 1)

The process of claim 1 wherein the solid porous material is carbon.

### Claim 6

In the continuous removal of ammonia gas from a mixed gas stream, the steps of providing a layer of acid containing electronic insulating material selected from the group consisting of non-electronic conducting acid and a porous, acid resistant material impregnated with non-electronic conducting acid, next to a gas permeable porous anode having an electrochemical potential imposed thereon, flowing the ammonia containing gas across the insulating material to convert the ammonia to an ammoniated salt which passes through the material to the anode with substantially no penetration of gaseous components into the material, and continuously converting the ammoniated salt to acid, hydrogen gas and nitrogen gas by holding the porous anode at an electrochemical potential sufficient to oxidize the ammoniated salt of the acid.

### Claim 7 (depends on 6)

The process of claim 6 wherein the gas stream contains hydrogen.

### Claim 8 (depends on 6)

The process of claim 6 wherein the potential is about 0.7 to about 1.0 volt.

### Claim 9 (depends on 6)

The process of claim 6 wherein the acid is phosphoric acid and the salt is ammonium dihydrogen phosphate.

### Claim 10 (depends on 6)

The process of claim 6 wherein the porous anode is carbon.

### Claim 11 (depends on 6)

The process of claim 6 wherein the acid containing electronic insulating material is selected from the group consisting of a pool of phosphoric acid, phosphoric acid impregnated silicon carbide and phosphoric acid impregnated polyaryl sulfone.