Ester functional organopolysiloxane lubricants and process
AssigneeGeneral Electric Company
InventorsBruce B. Hardman, Frank J. Traver
Life of this patent
Estimating the term…
Abstract
Organopolysiloxane lubricant compositions comprising a polysiloxane chain containing silicon-bonded hydrocarbon radicals and silicon-bonded ester radicals. The ester functional organopolysiloxanes are obtained by reacting an allyl ester, by Si-olefin addition, with an organohydrogenpolysiloxane in the presence of a platinum catalyst.
Claims7
An ester functional organopolysiloxane lubricant composition having the general formula:
- (CH.sub.3).sub.3 SiO[R.sub.2 SiO].sub.x [(Q)SiR].sub.y [R'SiO.sub.1.5 ].sub.z Si(CH.sub.3).sub.3
- where R and R' are selected from the group consisting of monovalent hydrocarbon radicals, halogenated monovalent hydrocarbon radicals and cyanoalkyl radicals, x has a value of from 0 to about 110, y has a value of from about 1 to 100, z has a value of from about 0.8 to about 5, and Q is an ester radical represented by the general formula:
- --CH.sub.2 --CH.sub.2 --(CH.sub.2).sub.p --C(O)O--V
- where the alkyl portion of the ester radical which bonds the C(O)O group to the organopolysiloxane chain comprises a straight chain or branched chain, said branched chain having alkyl or aryl radicals attached thereto, p has a value of from 1 to about 30 and V is selected from the group consisting of
- --(CH.sub.2).sub.q --(OCH.sub.2 CH.sub.2).sub.r --O--CH.sub.3 (a)
- where r has a value of from 1 to about 10,
- --(CH.sub.2).sub.q --O--CH.sub.3, (b)
- --CH.sub.3, (c)
- --(CH.sub.2).sub.q --CH.sub.3, (d)
- where the alkyl group modified by q in the above ester radical comprises a straight chain or a branched chain, said branched chain having an alkoxy group attached thereto, and where q has a value of from 1 to about 10,
- --(CH.sub.2 --CH.sub.2 --O).sub.s --H (e)
- where s has a value of from 1 to about 30, and
- --(CH.sub.2 --CH.sub.2 --O).sub.t --(CH.sub.2 (CH.sub.3)C(H)O).sub.u H (f)
- where t and u have a value of from 1 to about 20.
An ester functional organopolysiloxane lubricant composition having the average structural formula:
- ##STR5##
An ester functional organopolysiloxane lubricant composition having the average structural formula:
- ##STR6##
Dependencies are inferred from the claim text.