Transparent copolyamide from isophorone diamine and substituted undecane diamine
AssigneeCiba-Geigy Corporation
InventorsJosef Pfeifer, Dieter Reinehr
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AssigneeCiba-Geigy Corporation
InventorsJosef Pfeifer, Dieter Reinehr
Estimating the term…
Transparent copolyamides are obtained by reacting a mixture (A) of isophoronediamine and isophthalic acid, terephthalic acid or a mixture of isophthalic acid and terephthalic acid with a mixture (B) of a diamine ##STR1## and terephthalic acid or a mixture of terephthalic acid and isophthalic acid or with a mixture (C) of a diamine ##STR2## and terephthalic acid or isophthalic acid or mixtures thereof, R', R" and R.sub.1 to R.sub.6 being as defined in the patent claim. The reaction can also be carried out with an excess of diamine and with addition of H.sub.3 PO.sub.2 or salts thereof or white phosphorus. The novel copolyamides are distinguished by good thermoplastic processability, low water absorption and good resistance to hydrolysis, and are useful for the production of transparent mouldings.
A thermoplastic, transparent copolyamide obtained by reacting a diamine of the formula I ##STR7## and an aliphatic diamine with isophthalic acid or terephthalic acid or amide-forming derivatives thereof or with a mixture of isophthalic acid and terephthalic acid or amide-forming derivatives thereof, which copolyamide has a reduced specific viscosity of not less than 0.5 dl/g, measured on an 0.5% solution in m-cresol at 25.degree. C., and is obtained by reacting a mixture (A) of the diamine of the formula I and isophthalic acid or terephthalic acid or mixtures or amide-forming derivatives thereof either with a mixture (B) of an aliphatic diamine of the formula II ##STR8## and terephthalic acid or an amide-forming derivative thereof or a mixture of terephthalic acid and isophthalic acid or amide-forming derivatives thereof in a molar ratio of terephthalic acid or derivative:
Dependencies are inferred from the claim text.