Process for producing olefinic copolymer rubbers
AssigneeJapan EP Rubber Co., Ltd.
InventorsKenya Makino, Hideo Sakurai, Masaru Watanabe, Toshiyuki Nishimura
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Abstract
In a process for producing a rubbery olefinic copolymer which comprises random-copolymerizing at least two olefins in the presence of a catalyst composed of (A) a titanium compound and (B) an organometallic compound of a metal of Groups I to III of the periodic table, the improvement wherein the titanium compound (A) of the catalyst is a solution of a solid titanium halide in a hydrocarbon solvent, a halogenated hydrocarbon solvent or a mixture of both, said solid titanium halide being rendered soluble in said solvent.
Claims9
A process for the production of a rubbery olefinic copolymer by copolymerization of at least two olefins which comprises copolymerizing at least two olefins in the presence of catalyst components (A) and (B) composed of
- (A) a liquid obtained by dissolving a solid titanium trichloride in a hydrocarbon, a halogenated hydrocarbon or a mixture thereof in the presence, as a solubilizing agent, of
- (1) 5-0.1 mol, based on 1 mol of titanium, of at least one ether compound represented by the formula
- R.sup.1 OR.sup.2
- wherein R.sup.1 and R.sup.2 are identical or different, and each represents an alkyl, alkenyl, aralkyl or aryl group having 1 to 12 carbon atoms, or
- (2) 10-0.01 mol, on the basis of 1 mol of titanium, of at least one compound selected from the group consisting of halogens, interhalogen compounds, halogen compounds of phosphorous or sulfur, and oxyhalogen compounds of phosphorous or sulfur and
- (B) an organic metal compound of a metal of Groups I-III in the periodic table being a liquid at room temperature, said copolymerization being effected by feeding to a reactor said catalyst components (A) and (B) in the form of a solution thereby obtaining a random copolymer made up of at least two of said olefinic comonomers, such that not one of the individual monomer units which make up the random copolymer exceeds 80% by weight of the random copolymer.
Dependencies are inferred from the claim text.