Dimensionally-stable polyurethane sponge and sponge-forming prepolymer
AssigneeW. R. Grace & Co.
InventorsJames L. Guthrie, Suze E. Arquette
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AssigneeW. R. Grace & Co.
InventorsJames L. Guthrie, Suze E. Arquette
Estimating the term…
An MDI based polyurethane foam having cellulose foam properties is produced by mixing together an aqueous phase which can optionally contain reinforcing fibers and surfactants and a resin phase comprising a prepolymer derived from a poly(oxy C.sub.2-4 alkylene)diol, an MDI containing isocyanate product having a functionality greater than 2.0 made of a mixture of MDI and isocyanate containing derivatives of MDI, and a monomeric polyol cross-linking agent having 3 or 4 hydroxyl equivalents per mole. The preferred polyol is trimethylolpropane and the preferred diol is Carbowax 1000. The diol and the polyol, such as trimethylolpropane, are present in a mole ratio in the range of 4:1 to 8:1 while the ratio of the isocyanate equivalents to the total hydroxyl equivalents is in the range of 3:1 to 4:1. The isocyanate containing product comprises more than 50% by weight of the prepolymer and Isonate 143L is the preferred isocyanate product. The foam has a minimal swell when wet and it does not curl upon drying.
A foamed sponge having minimal swell when wet and which does not curl upon drying made by mixing together and reacting an aqueous phase and
A prepolymer, for use in making a foamed sponge, comprising the reaction product of
Dependencies are inferred from the claim text.