# US 4,377,469 A · Maintaining catalytic activity of sodium aluminosilicates

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- Number: US 4,377,469 A
- Document ID: US4377469A
- Status: Granted
- Kind: A
- Application number: 06/307,055
- Filed: 1981-09-30
- Granted: 1983-03-22
- Earliest claimed: 1981-09-30
- Assignees: Mobil Oil Corporation
- Inventors: David S. Shihabi
- Web page: https://patentgrep.com/patent/US4377469A

## CPC

- C10G 45/64: containing crystalline alumino-silicates, e.g. molecular sieves
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

The aging of a dewaxing catalyst, such as a presteamed, sodium-exchanged ZSM-5 type zeolite, is improved when the dewaxing is being conducted in the presence or absence of added gas if water or a water precursor is admixed with the feedstock.

## Claims

### Claim 1

A process for reducing the pour point of a was containing mineral oil to a predetermined value which comprises:
contacting a mixture of said mineral oil and added water or a water precursor with a catalyst having an alpha value less than about 10, in the presence or absence of added gas, under conversion conditions effective to reduce the pour point of said oil to said predetermined value,
said catalyst having been prepared from a composition comprising a precursor crystalline aluminosilicate having a silica-alumina ratio greater than 12, a constraint index between about 1 and about 12 and an alpha value greater than about 20, said preparation including steaming said precursor to reduce its alpha value to not less than about 10 and ion-exchanging said steamed precursor with an alkali metal cation under conditions effective to further reduce its alpha value to less than about 10,
said water or said water precursor being present in an amount effective to reduce the conversion temperature required to effect the reduction of the pour point of said mineral oil to said predetermined value in the absence of said water or said water precursor.

### Claim 2 (depends on 1)

A process according to claim 1 wherein said precursor crystalline aluminosilicate is ZSM-5 zeolite in hydrogen or ammonium form.

### Claim 3 (depends on 1)

A process according to claim 1 wherein said catalyst has an alpha value less than about 1.

### Claim 4 (depends on 1)

A process according to claim 1 wherein said alkali metal cation is sodium.

### Claim 5 (depends on 1)

A process according to claim 1 wherein said alkali metal cation is lithium.

### Claim 6 (depends on 1)

A process according to claim 1 wherein the pour point reduction is conducted in the presence of added gas.

### Claim 7 (depends on 6)

A process according to claim 6 wherein the gas addition is 0 to 15,000 scf/bbl.

### Claim 8 (depends on 6)

A process according to claim 6 wherein the added gas comprises hydrogen, C.sub.1 -C.sub.3 hydrocarbon or mixtures thereof.

### Claim 9 (depends on 8)

A process according to claim 8 wherein the added gas comprises hydrogen.

### Claim 10 (depends on 8)

A process according to claim 8 wherein the added gas comprises methane.

### Claim 11 (depends on 1)

A process according to claim 1 wherein the wax-containing mineral oil is whole crude, reduced crude or gas oil.

### Claim 12 (depends on 1)

A process according to claim 1 wherein the water or water precursor is periodically admixed with the mineral oil and the effective amount, based on water, is between about 0.01 and about 30 volumes of water per volume of catalyst.

### Claim 13 (depends on 1)

A process according to claim 1 wherein the water or water precursor is continuously admixed with the mineral oil and the effective amount, based on water, is less than about 5 volume percent of said mineral oil.