Cured rubber skim stocks having improved metal adhesion and metal adhesion retention by use of organo-metal complexes and halogenated polymer
AssigneeThe Firestone Tire & Rubber Company
InventorsJames A. Davis, Robert C. Koch
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Abstract
This invention is directed to an improved rubber skim stock composition and a product containing the skim stock having improved adhesion and adhesion retention with metallic reinforcement cords such as brassed steel. The invention composition comprises a conventional vulcanizable rubber skim stock, at least one halogenated polymer and at least one organo complex of cobalt or nickel. Tests conducted with brass-plated and zinc-plated steel cords showed improved metal adhesion and metal adhesion retention with use of the improved rubber skim stock of this invention when compared to control formulations.
Claims11
In an improved cured rubber skim stock of conventional composition, bonded to at least one metal member contained in it, the improvement which comprises incorporating into said stock prior to curing a minor, but metal adhesion - promoting and - retaining amount of the combination of (a) about 5-30 phr of at least one halogenated polymer and (b) about 0.25-8.0 phr of at least one organo-cobalt or about 0.5-12 phr of organo-nickel complex, said halogenated polymer (a) being chlorobutyl rubber, bromobutyl rubber, fluorocarbon elastomer of specific gravity about 1.86, or chlorosulfonated polyethylene polymer containing about 43% chlorine and 1.0 to 1.1% sulfur and having a specific gravity of about 1.26 at 25.degree. C., and said complex (b) being Manobond C represented by the general formula ##STR2## wherein each R is an alkyl radical of from 9 to 12 carbons or organo carboxylate complexes of cobalt or nickel with aliphatic fatty acids having from 2 to about 20 carbon atoms.
Dependencies are inferred from the claim text.