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AssigneeSnamprogetti S.p.A.
InventorsVincenzo Lagana', Francesco Saviano, Piero Bisi
Estimating the term…
An improved process is disclosed for preparing gases containing hydrogen and nitrogen and which is especially suitable for the synthesis of ammonia. Using natural gas or virgin naphtha as the starting materials, the reforming reaction with steam takes place in two serially arranged stages, the first of which occurs at an inlet temperature of from 400.degree. C. to 650.degree. C. and an exit temperature of from 650.degree. C. to 750.degree. C., a conversion of from 20% to 50% being effected, the second stage working at an exit temperature of from 750.degree. C. to 850.degree. C. and the conversion being increased up to 70%. Air reforming is carried out under conditions at which the exit temperature of the gas is between 920.degree. C. and 1050.degree. C. and the sensible heat of the effluent gases from the air reforming at such temperature condition is employed to activate the second steam reforming stage. Tube bundle heat-exchangers, the tubes of which are filled with an appropriate catalyst, are used.
A process for the preparation of gases which contain hydrogen and nitrogen starting from natural gas or virgin naphtha by steam reforming in two stages and subsequent air reforming in one stage, comprising feeding said natural gas or virgin naphtha to the first steam reforming stage at a temperature of from 400.degree. C. to 650.degree. C. and converting from 20% to 50% thereof in said first steam reforming stage, removing the partially converted natural gas or virgin naphtha from said first steam reforming stage at a temperature between 650.degree. C. and 750.degree. C. and feeding the same to the second steam reforming stage, raising the conversion of said partially converted natural gas or virgin naphtha up to 70% in said second steam reforming stage, removing the partially converted natural gas or virgin naptha from said second steam reforming stage at a temperature between 750.degree. C. and 850.degree. C. and feeding the same to the air reforming stage, further converting the partially converted natural gas or virgin naphtha with burning air in said air reforming stage, raising and maintaining the temperature thereof to a temperature between 920.degree. C. and 1050.degree. C. in said air reforming stage, producing a gas having a temperature which is sufficient to actuate the second stage of said steam reforming and employing the sensible heat of the effluent gases from the air reforming to actuate the second stage of steam reforming.
A process for the preparation of gases which contain hydrogen and nitrogen starting from natural gas or virgin naphtha comprising the steps of:
Dependencies are inferred from the claim text.