# US 4,375,444 A · Method for the elimination of circumferential stress cracks in spun polyesters

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- Number: US 4,375,444 A
- Document ID: US4375444A
- Status: Granted
- Kind: A
- Application number: 06/341,405
- Filed: 1982-01-21
- Granted: 1983-03-01
- Earliest claimed: 1979-09-20
- Assignees: The Goodyear Tire & Rubber Company
- Inventors: William O. Deeken
- Web page: https://patentgrep.com/patent/US4375444A

## CPC

- D06M 7/00: {Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins (D06M10/00 takes precedence; treating fibres or filaments made of glass, mineral -, or slag wool C03C; carbon fibres D01F11/10)}
- D06M 2200/40: Reduced friction resistance, lubricant properties; Sizing compositions
- D06M: TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS

## Abstract

A method for the elimination of circumferential stress cracks that occur during production of spun polyesters is provided. The cracks are eliminated by the use of an organic solvent miscible with the lubricating emulsion applied during the finish operation before draw twisting of the spun polyester. The organic solvent may be kerosene or mineral oil or solutions containing the same.

## Claims

### Claim 1

A process to minimize circumferential stress cracking in spun polyester filaments, comprising:
(a) mixing a miscible non-aqueous solution of a fiber finishing emulsion and an organic solvent, said emulsion having emulsifiers, lubricating oils, antistat oils and heat stabilizers; said organic solvent selected from the group consisting of: mineral oil, kerosene, and combinations thereof;
(b) melt spinning polyester fiber;
(c) contacting said solution with the fiber;
(d) storing the spun polyester; and
(e) draw twisting the spun polyester to produce a spun polyester yarn having minimal circumferential stress cracks.

### Claim 2 (depends on 1)

A process according to claim 1, wherein said contacting step further comprises the stages of:
(a) moving the fiber against means for communicating said solution with the fiber;
(b) transferring said solution with each fiber; and
(c) absorbing said solution into each fiber, so that said solution lubricates each fiber for said draw twisting increasing the tenacity and tensile strength of each fiber and said organic solvent prevents crystallization of the surface of each fiber which create circumferential stress cracks.

### Claim 3 (depends on 1)

A process according to claim 1, wherein said storing may exist from about 24 hours to about 90 hours.