Solvent dewaxing process
AssigneeTexaco Inc.
InventorsCharles W. Harrison, Herbert J. Pitman, Avilino Sequeira, Jr., John D. Begnaud
Life of this patent
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Abstract
A process for dewaxing a petroleum oil stock with a liquid solvent employing direct heat exchange cooling of solvent-oil mixture with an immiscible liquid chilling medium.
Claims12
In a process for dewaxing a waxy lubricating oil stock by cooling said stock in the presence of a dewaxing solvent to a temperature effective for the removal of wax therefrom by filtration the improvement which comprises introducing said oil stock into a chilling zone into countercurrent liquid-liquid contact with a chilled immiscible heat exchange liquid, separating said heat exchange liquid from resulting chilled oil stock, introducing dewaxing solvent into admixture with said chilled oil stock at substantially dewaxing temperature, separating by filtration solidified wax from resulting dewaxed oil and solvent, recovering a mixture of solvent and oil of diminished wax content from said filtration step, and passing said dewaxed oil/solvent mixture at substantially said dewaxing temperature into intimate countercurrent liquid-liquid contact with immiscible liquid coolant from said cooling zone thereby chilling said heat exchange liquid for reuse in said cooling zone and warming said mixture of dewaxed oil and solvent, separating said warmed dewaxed oil and solvent from said heat exchange liquid, chilling said heat exchange liquid to substantially dewaxing temperature and reintroducing said chilled heat exchange liquid into said cooling zone.
The method of separating wax from a wax-bearing oil which comprises:
- (a) mixing said wax-bearing oil with a dewaxing solvent,
- (b) passing the resulting oil-solvent mixture in a first cooling zone into direct countercurrent contact with an immiscible liquid chilling medium effecting warming of said immiscible liquid chilling medium and concomitant cooling of said oil-solvent mixture to a temperature at which wax crystallizes forming a slurry of wax in oil-solvent mixture,
- (c) separating said slurry from said immiscible liquid,
- (d) filtering said slurry thereby forming a first filter cake of slack wax containing wax crystals and occluded oil-solvent mixture and a filtrate comprising dewaxed oil and solvent,
- (e) passing said filtrate into direct heat exchange with warmed immiscible liquid from step (b) effecting cooling of said immiscible liquid and warming of said filtrate,
- (f) recovering cooled immiscible liquid from said filtrate,
- (g) further cooling said immiscible liquid from step (f), and
- (h) passing said cooled immiscible liquid from step (g) into direct heat exchange with said oil-solvent mixture in said first cooling zone as the source of immiscible liquid therefor.
Dependencies are inferred from the claim text.