Process for the manufacture of dianthraquinonyl-N,N'-dihydroazine
AssigneeCiba-Geigy Corporation
InventorAthanassios Tzikas
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Abstract
A process for the manufacture of dianthraquinonyl-N,N'-dihydroazine, which comprises reacting 1-nitroanthraquinone in mixtures of water, alcohols and alkali metal hydroxides at elevated temperature with hydrazine or hydroxylamine compounds, subsequently removing the alcoholic constituents from the reaction mixture, adding dimethyl sulfoxide, and, if desired, further amounts of alkali metal hydroxides, and bringing the reaction to completion at elevated temperature.
Claims11
A one-batch process for the manufacture of dianthraquinonyl-N,N'-dihydroazine, which comprises reacting 1-nitroanthraquinone in a mixture of (a) water or a mixture of water and at least one alcohol and (b) an alkali metal hydroxide or a mixture of alkali metal hydroxides at a temperature of between room temperature and the boiling temperature of the reaction mixture with hydrazine, hydrazine hydrate, methyl hydrazine, ethyl hydrazine, phenyl hydrazine, hydrazinium chloride, hydrazinium dichloride, hydrazinium sulfate, hydrazinium bromide, benzenesulfonyl hydrazine, hydroxylamine, hydroxylamine hydrochloride, hydroxylammonium sulfate or hydroxylamine sulfonic acid, subsequently removing any alcoholic constituents present from the reaction mixture, adding to the reaction mixture dimethyl sulfoxide or dimethyl sulfoxide and a further amount of alkali metal hydroxide, and bringing the reaction to completion at a temperature between 80.degree. and 140.degree. C.
Dependencies are inferred from the claim text.