Back to results
US 4,374,953 AGranted
Method for preparing polyacetals and polyketals by emulsion polymerization
AssigneeDow Corning Corporation
InventorsYungnien J. Chou, John C. Saam
Life of this patent
Estimating the term…
Abstract
Polyacetals and polyketals are prepared by reacting emulsified carbonyl compounds with emulsified polyfunctional alcohols in aqueous media and in the presence of specified polycondensation catalysts. Coherent films of the resultant polymers can be applied to substrates from aqueous or non-aqueous media.
Claims37
A method for preparing polyacetals and polyketals by emusion polymerization, said method comprising the steps of
- (1) emulsifying in an aqueous medium a mixture comprising
- (a) at least one reagent containing at least 5 carbon atoms and 2 or more hydroxyl groups or 2 or more esterified hydroxyl groups of the formula RCOO-- where R is alkyl and contains from 1 to 3 carbon atoms and the hydroxyl or esterified hydroxyl groups are bonded to aliphatic or cycloaliphatic carbon atoms,
- (b) at least one carbonyl compound containing at least 5 carbon atoms or a reaction product of said carbonyl compound and a water-soluble monofunctional alcohol containing from 1 to 3 carbon atoms, said carbonyl compound being selected from the group consisting of mono- and polyfunctional aldehydes and mono- and polyfunctional ketones wherein the carbonyl groups of the carbonyl compound are bonded to aliphatic or cycloaliphatic carbon atoms, and
- (c) at least one polycondensation catalyst in an amount effective to accelerate the rate of reaction of (a) with (b), and
- (2) thereafter allowing (a) and (b) to react until the desired product is obtained.
2 more elements
Dependencies are inferred from the claim text.