Magnesium disiloxide compounds
AssigneeConoco Inc.
InventorsCharles T. Berge, Mark P. Mack, Charles M. Starks
Life of this patent
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Abstract
Novel magnesium disiloxide compounds and methods for their preparation are disclosed. The magnesium disiloxides so obtained are useful starting materials for the preparation of active catalysts for olefin polymerizations.
Claims12
A method of preparing a magnesium disiloxide of the general formula ##STR9## by contacting a silanol of the general formula ##STR10## with magnesium metal in an inert solvent, allowing reaction to occur, then recovering magnesium disiloxide, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are, independently, hydrogen, alkyl groups, cycloalkyl groups, alkaryl groups, aralkyl groups, aryl groups or bicycloalkyl groups.
A method of preparing a magnesium disiloxide of the general formula ##STR11## by contacting a silanol of the general formula ##STR12## with a magnesium compound of the general formula R.sup.7 --Mg R.sup.8 in an inert solvent, allowing reaction to occur, then recovering magnesium disiloxide, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 are, independently, hydrogen, alkyl groups, cycloalkyl groups, aralkyl groups, aryl groups or bicycloalkyl groups each containing from 1 to 20 carbon atoms.
A method of preparing a magnesium disiloxide of the general formula ##STR13## by contacting a silyl chloride of the general formula ##STR14## with magnesium hydroxide in an inert solvent to initiate a reaction, allowing the reaction to occur, then recovering magnesium disiloxide, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are, independently, hydrogen, alkyl groups, cycloalkyl groups, aralkyl groups, aryl groups of bicycloalkyl each containing from 1 to 20 carbon atoms or hydride.
A method of preparing a magnesium disiloxide of the general formula ##STR15## by contacting a silating agent of general formula ##STR16## with magnesium hydroxide in an inert solvent to initiate a reaction, allowing the reaction to occur, then recovering the magnesium disiloxide, wherein n is 1 or 2 and where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are, independently, hydrogen, alkyl groups, cycloalkyl groups, alkaryl groups, aralkyl groups, aryl groups or bicycloalkyl groups, and wherein when n=1, Z is selected from the group consisting of ##STR17## and when n=2, Z is selected from the group consisting of ##STR18##
A method of preparing a magnesium disiloxide of the general formula ##STR19## by contacting a silanate of the general formula ##STR20## where M is a Group I metal, with at least one magnesium halide in an inert solvent to initiate a reaction, allowing the reaction to occur, then recovering magnesium disiloxide, wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are, independently, hydrogen, alkyl groups, cycloalkyl groups, aralkyl groups, aryl groups or bicycloalkyl groups each containing from 1 to 20 carbon atoms.
A catalyst prepared by
- (a) placing magnesium disiloxides of the general formula ##STR21## in contact with at least one material selected from the group consisting of Mg and MgX.sub.2 in an inert hydrocarbon diluent;
- (b) adding a Group 4b to Group 8 transition metal compound to form a solid precipitate, then;
- (c) recovering the solid precipitate as a catalyst
- wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are, independently hydrogen, alkyl groups, aralkyl groups, alkaryl groups, cycloalkyl groups, aryl groups or bicycloalkyl groups containing from 1 to 20 carbon atoms, and wherein X is chlorine, bromine or iodine.
Dependencies are inferred from the claim text.