Alkanolamine ester of 1,1-biphenyl-2,2-diyl-and alkylidene-1,1-biphenyl-2,2-diyl-cyclic phosphites
AssigneeCiba-Geigy Corporation
InventorsJohn D. Spivack, Martin Dexter, Stephen D. Pastor
Life of this patent
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Abstract
The title compounds are prepared by reacting alkylated 1,1'-biphenyl-2,2'-diol or alkylated 2,2'-alkylidene-bis-phenol with phosphorus trichloride in an organic solvent and then reacting the intermediate phosphorochlorodite with an alkanolamine. Said phosphites are useful as stabilizers of organic polymers and lubricating oils, especially as processing stabilizers for polyolefins, elastomers, polyesters and polycarbonates.
Claims8
A composition of matter comprising an organic material subject to oxidative, thermal and actinic degradation stabilized with an effective stabilizing amount of a compound corresponding to the formula ##STR21## wherein m, n and p are each 1, m is 2 and n is 1 and p is 0 or m is 3 and n and p are 0, and wherein
- R is alkyl of from 1 to 18 carbon atoms,
- R.sup.1 is hydrogen or alkyl of from 1 to 18 carbon atoms,
- R.sup.2 is a direct bond or alkylene of from 1 to 12 carbon atoms,
- A is alkylene of from 1 to 6 carbon atoms, or cycloalkylene of 5 to 6 carbon atoms,
- R.sup.3 is alkyl of 1 to 18 carbon atoms, or ##STR22## wherein Y is ##STR23## A' is alkylene of 1 to 6 carbon atoms or cycloalkylene of 5 to 6 carbon atoms,
- m' is 1 or 2,
- p is 0 or 1, and
- q is 0-5,
- with A, R, R.sup.1, R.sup.2 being as previously defined;
- provided that when p and q are 0, -N-A'-N can be a diazacycloalkyl group of 2 to 10 carbon atoms, or
- when m is 1 and p is 0, N-R.sub.3 is a azacycloalkyl group of 2 to 10 carbon atoms or an azaoxacycloalkyl group of 3 to 7 carbon atoms;
- and
- R.sup.4 is alkyl of 1 to 18 carbon atoms;
- together with a phenolic antioxidant selected from the group consisting of 6,6'-ethylidene-bis(2,4-di-tert.butylphenol), 6,6'-methylene-bis(2,4-di-tert.butylphenol) and 1,3,5-tris(4-tert.butyl-3-hydroxy-2,6-dimethylbenzyl)isocyanurate.
The composition of claim 17, wherein said synthetic polymer is a polyolefin homopolymer or copolymer.
The composition of claim 18, wherein said polyolefin is selected from the group consisting of polyethylene, polypropylene, polyisobutylene, poly(butene-1), poly(pentene-1), poly(methylbutene-1) and poly(4-methylpentene-1).
Dependencies are inferred from the claim text.