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US 4,369,283 AGranted
High solids can coating composition containing epoxy, acrylic and aminoplast resins
AssigneeE. I. Du Pont de Nemours and Company
InventorLili W. Altschuler
Life of this patent
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Abstract
A high solids coating composition comprising defined acrylics, polyester, reactive diluent, aminoplast, catalyst and pigment including talc and TiO.sub.2 is particularly suitable for use as an exterior can coating which is baked repetitively to cure multiple ink applications.
Claims11
A high solids exterior can coating composition consisting essentially of:
- A. a vehicle blend consisting essentially of:
- 1. from 5 to 22% by weight of acrylic polymer having a weight average molecular weight determined by gel permeation chrometography using a polystyrene standard, of from at least 50,000 to 90,000,
- 2. from 25 to 50% by weight of polyester having the structure:
- ##STR1## or the isomer through the secondary hydroxyl group or mixtures thereof, wherein X= ##STR2## and wherein n=0-10 and at least 70% by weight is n=3 or less provided that only a maximum of 25% by weight of n=0;
- and wherein the polyester has a number average molecular weight not exceeding 1,000, determined by gel permeation chromatography using a polypropylene glycol standard;
- 3. from 5 to 15% by weight of castor oil which has not been dehydrated;
- 4. from 20 to 50% of an aminoplast resin;
- 5. pigments comprising TiO.sub.2 and talc in proportions of from 10 to 90% by weight of each, the ratio of pigments to vehicle solids being in the range of 0.8:1 to 1.4:1 by weight;
- and
- 6. from 0.2 to 2.0% by weight of a catalyst which is a blocked sulfonic acid catalyst wherein the sulfonic acid is selected from the group consisting of methane sulfonic acid, paratoluene sulfonic acid alkyl benzene sulfonic acid wherein the alkyl group contains 2-12 carbon atoms, and 2-methacryloxyethyl sulfonic acid, its homopolymers and copolymers;
- and
- B. aliphatic and aromatic hydrocarbon solvents;
- said coating composition having a solids contents of at least 70% by weight.
10 more elements
Dependencies are inferred from the claim text.