Unsaturated polyester resin composition
AssigneeNippon Oil and Fats Co., Ltd.
InventorsNorihisa Ujikawa, Masaharu Nakayama
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Abstract
An unsaturated polyester resin composition which is obtained by incorporating a thermoplastic random-copolymer having peroxycarbonate groups in the molecule thereof into an unsaturated polyester resin, which composition is excellent in low shrinkage characteristics and it is not weakened in mechanical strength.
Drawings
Claims5
An unsaturated polyester composition comprising:
- (a) 100 parts by weight of an .alpha.,.beta.-ethylenically unsaturated polyester;
- (b) from 3 to 30 parts by weight of a random copolymer prepared by radical copolymerization, at a polymerization temperature of from 0.degree. to 110.degree. C., in the presence of a radical polymerization initiator, of (1) an unsaturated peroxycarbonate having the formula ##STR8## wherein R.sub.1 is hydrogen or C.sub.1-4 alkyl, R.sub.2 and R.sub.3 each is a C.sub.1-4 alkyl, and R.sub.4 is a C.sub.1-12 alkyl or C.sub.3-12 cycloalkyl, with (2) one or a mixture of two or more ethylenically unsaturated monomers selected from the group consisting of vinyl acetate, vinyl chloride, ethylene, allylacetate, allylchloroacetate, vinyl chloroacetate, butyl 3-butoxyacrylate, allylalcohol, 1,2-dichloroethylene, dibutyl maleate, diethyl maleate, isopropyl maleate, dimethyl maleate and methyl maleate, said ethylenically unsaturated monomers having Alfred-Price Q values of not more than 0.2, said random copolymer having a mean molecular weight of from 1.times.10.sup.4 to 3.times.10.sup.5 and containing from 0.5 to 20% by weight of peroxycarbonate groups, said random copolymer having units of the formula ##STR9## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 have the same meanings as defined above, and units derived from said ethylenically unsaturated monomer or monomers;
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- (c) from 27 to 190 parts by weight or one or a mixture of two or more polymerizable monomers selected from the group consisting of styrene, vinyltoluene, chlorostyrenes, diallylphthalate, vinyl acetate, acrylic acid esters and methacrylic acid esters.
Dependencies are inferred from the claim text.