Water-resistant alkaline corrugating adhesive composition
AssigneeNational Starch and Chemical Corporation
InventorsMichael A. Silano, Robert D. Featherston
Life of this patent
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Abstract
A crosslinking additive for imparting water resistance to starch-based corrugating adhesive compositions is prepared by reacting acetone and formaldehyde under aqueous alkaline conditions at 20.degree.-80.degree. C. in a molar ratio of 1 mole acetone to about 2 to 5.5 moles formaldehyde, adding to the reaction mixture at least an effective amount of dihydroxyethylene urea to scavenge the free formaldehyde in the mixture, and reacting until the amount of unreacted formaldehyde remaining is reduced to about 0.1-2%. The crosslinking additive thus obtained, which is low in free formaldehyde, may be added directly to a starch-based corrugating adhesive or may be first mixed with dimethylol dihydroxyethylene urea.
Claims11
In a process for preparing a crosslinking additive for imparting water resistance to starch-based corrugating adhesive compositions wherein acetone and formaldehyde are reacted in a molar ratio of 1 mole of acetone to about 2 to 5.5 moles of formaldehyde under aqueous alkaline conditions at about 20.degree.-80.degree. C. to obtain a water-soluble acetone-formaldehyde condensate containing about 1-10% unreacted formaldehyde, the improvement which comprises adding to said water-soluble acetone-formaldehyde condensate at least an effective amount of dihydroxyethylene urea to react with the unreacted formaldehyde present therein and allowing the reaction to proceed at about 20.degree.-80.degree. C. until the unreacted formaldehyde remaining is reduced to about 0.1-2% by weight.
A water-resistant alkaline curing, starch-based corrugating adhesive composition comprising:
- A. from about 10 to 40%, based on total weight of the adhesive, of starch, this including the ungelatinized as well as the gelatinized portions of the starch;
- B. from about 0.3 to 5%, based on total weight of the starch, of an alkali;
- C. from about 54 to 89%, based on total weight of the adhesive, of water;
- and
- D. from about 0.3 to 10%, based on total weight of the starch, dry basis, of a crosslinking additive prepared by reacting acetone and formaldehyde in a molar ratio of 1 mole of acetone to about 2 to 5.5 moles of formaldehyde under aqueous alkaline conditions at about 20.degree.-80.degree. C. to obtain a water-soluble acetone-formaldehyde condensate containing about 1-10% unreacted formaldehyde;
- adding to the condensate at least an effective amount of dihydroxyethylene urea to react with the unreacted formaldehyde present therein;
- and allowing the reaction to proceed at about 20.degree.-80.degree. C. until the unreacted formaldehyde remaining is reduced to about 0.1-2% by weight.
Dependencies are inferred from the claim text.