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US 4,365,099 AGranted
Process for the production of bisphenols
AssigneeGeneral Electric Company
InventorsGary R. Faler, Ashok K. Mendiratta
Life of this patent
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Abstract
A method of improving the performance of cationic exchange catalysts used in the production of bisphenols from phenolic compounds and carbonyl compounds by pretreating the phenolic compound with a chelating resin to remove metallic impurities.
Claims14
In a method for the condensation of a carbonyl compound selected from the class consisting of, cycloheptanone, acetophenone, benzophenone and compounds of the general formula:
- ##STR6## wherein X is independently selected from the class consisting of hydrogen, fluorine, monovalent alkyl groups, from 1 to 8 carbon atoms, aryl groups and alkaryl groups with a phenolic compound of the general formula:
- ##STR7## wherein R is independently selected from the class consisting of hydrogen fluorine monovalent alkyl groups from 1 to 8 carbon atoms, aryl groups and alkaryl groups for the production of bis(hydroxyaryl) compounds, whereby at least two moles of said phenolic compound are caused to react with one mole of said carbonyl compound in the presence of a cationic exchange resin in a reaction zone;
- the improvement comprising pretreating said phenolic compound by contacting said phenolic compound with a chelating resin to remove impurities and thereafter mixing said phenolic compound with said carbonyl compound.
The method for making bis(hydroxyaryl) compounds which comprises
- (1) pretreating a phenolic compound by passing the phenolic compound through a bed containing a chelating resin;
- (2) adding a carbonyl compound to the pre-treated phenolic compound;
- and
- (3) passing the phenolic-carbonyl mixture through a reaction zone containing a neutralized cationic exchange resin to effect a condensation reaction;
- and
- (4) removing the phenolic-carbonyl condensation products.
3 more elements
Dependencies are inferred from the claim text.