Crosslinkable bis-imidyl derivatives
AssigneeCiba-Geigy Corporation
InventorsRoland Darms, Vratislav Kvita, Gerd Greber
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Abstract
New crosslinkable bis-imidyl derivatives are described which can be produced by reaction of imidylphthalic acid derivatives, such as maleimidyl-phthalic acid anhydrides, with monomeric, oligomeric or polymeric diamines. The new crosslinkable bis-imidyl derivatives can be used for producing crosslinked polymers which are distinguished, in particular, by their stability to oxidation and to heat.
Claims7
A crosslinkable compound of the formula ##STR25## wherein the X s independently of one another represent hydrogen or, if the radical ##STR26## is in the 4-position of the benzene ring, also --COR.sub.2, the R.sub.2 s independently of one another represent hydroxyl, phenoxy;
- phenoxy substituted by one or two nitro groups, by one alkyl of 1 to 2 carbon atoms, by one alkoxy of 1 to 2 carbon atoms or by two or five halogen atoms;
- alkoxy of 1 to 18 carbon atoms or an O-M+ group,
- the R.sub.1 s independently of one another have the same meaning as the R.sub.2 s or two adjacent R.sub.1 s together represent the --O-- grouping,
- the A s independently of one another represent a radical of the formula ##STR27## R.sub.3 and R.sub.4 independently of one another represent hydrogen, chlorine, bromine or methyl,
- M+ represents an alkali metal cation, a trialkylammonium cation having 3-24 carbon atoms, or the benzyltrimethylammonium or tetramethylammonium cation,
- Q represents --NH--, and
- Y represents a structural element of the formula ##STR28## wherein a represents a number from 1-100, Z represents alkylene of 2 to 10 carbon atoms, 1,3-phenylene, 1,4-phenylene, the 4,4'-diphenylmethane group, the 4,4'-diphenylsulfone group or the 4,4'-diphenyl ether group, and
- Z.sub.1 represents a benzenetriyl group, in which the ##STR29## group is bound to ortho carbons of Z.sub.1.
Dependencies are inferred from the claim text.