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US 4,365,055 AGranted
Process for producing substantially linear carbonate polymer
AssigneePPG Industries, Inc.
InventorDarold L. Madigan
Life of this patent
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Abstract
In the preparation of a substantially linear carbonate polymer wherein carbonic dihalide is introduced to a substantially anhydrous solution comprising at least one substituted or unsubstituted 1,3-propanediol, the coproduction of cyclic carbonate is reduced by the presence in the solution of a catalytic amount of nitrogen-containing, hydrohalide salt-forming, thermally regenerable organic catalyst. The preferred carbonic dihalide is phosgene and the preferred catalyst is pyridine.
Claims22
A process for producing substantially linear carbonate polymer comprising:
- a. introducing carbonic dihalide to substantially anhydrous solution comprising inert organic solvent, at least one substituted or unsubstituted 1,3-propanediol and a catalytic amount of nitrogen-containing, hydrohalide salt-forming, thermally regenerable organic catalyst, while the temperature of said solution is in the range of from about 70.degree. C. to about 225.degree. C.;
- and
- b. removing hydrogen halide from the vicinity of said solution.
Dependencies are inferred from the claim text.