Vapor permeation curable polyester resin coating compositions for flexible substrates
AssigneeAshland Oil, Inc.
InventorJames R. Blegen
Life of this patent
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Abstract
Disclosed is a coating composition rapidly curable at room temperature in presence of a vaporous tertiary amine catalyst and possessing a flexibility sufficient for a zero-T bend on metal and a mar resistance of at least about 2,000 grams as borne by the edge of a nickel passed on said film. The coating composition is a phenolic-terminated-polyester and multi-isocyanate curing agent (at least about 10% aromatic isocyanate content) dispersed in a fugitive organic solvent, and a mar-resisting aid of an organic compound physically incompatible in said coating composition and having an effective chain length of at least about 12 carbon atoms. Application of the coating composition preferably is on a flexible substrate such as a thermoplastic substrate.
Claims20
A coating composition rapidly curable at room temperature in the presence of a vaporous tertiary amine catalyst and possessing a pot life of at least about 4 hours in an open pot, a cured film thereof at a thickness of between about 0.1 and 0.5 mils possessing a flexibility sufficient for a zero T-bend on metal, and a mar resistance of at least about 2,000 grams as borne by the edge of a nickel passed over said cured film, comprising:
- (A) an aromatic hydroxyl-functional condensation product having an acid number of less than about 10 and made by condensing the following ingredients in the indicated molar proportions or double thereof except for the phenolic-functional carboxylic acid:
- (1) between about 1 and 2 moles of a C.sub.2 -C.sub.12 linear aliphatic dibasic acid,
- (2) between about 1 and 2 moles of an ortho or meta aromatic dicarboxylic acid or anhydride thereof,
- (3) between about 1 and 4 moles of a C.sub.2 -C.sub.6 alkylene glycol,
- (4) between about 1 and 2 moles of a sterically hindered diol,
- (5) between about 1 and 2 moles of a mono-epoxide or diol having a pendant C.sub.8 -C.sub.22 hydrocarbyl group, and
- (6) between about 1 and 2 moles of a phenolic-functional carboxylic acid;
- (B) a multi-isocyanate comprising:
- (1) between about 10 and 80 percent by weight of an aromatic multi-isocyanate, and
- (2) between about 90 and 20 percent by weight of an aliphatic multi-isocyanate;
- (C) a volatile organic solvent for said condensation product and for said multi-isocyanate, and
- (D) a mar-resisting agent of an organic compound physically incompatible in said coating composition and having an effective chain length of at least about 12 carbon atoms;
- the ratio of aromatic hydroxyl equivalents of said condensation product to the isocyanate equivalents of said multi-isocyanate being between about 1:1 and 1:1.7, said condensation product containing substantially no aliphatic hydroxyl groups, and said condensation product having a phenol functionality of at least 2.
An improved coating composition of a phenolic-function polyester resin and multi-isocyanate curing agent containing at least about 10% aromatic multi-isocyanate dispersed in fugitive organic solvent therefor, said composition rapidly curable at room temperature in the presence of a vaporous tertiary amine catalyst, the improvement for increasing the mar resistance of a cured film of said coating composition on a flexible substrate which comprises said composition containing a mar-resisting proportion of an organic compound physically incompatible in said composition and having an effective chain length of at least about 12 carbon atoms.
Dependencies are inferred from the claim text.