One-step syntheses of uranium hexamethoxide and mixed methoxy uranium (VI) fluorides from uranium hexafluoride and two-step synthesis of uranium hexamethoxide from uranium tetrachloride
AssigneeNorthwestern University
InventorsTobin J. Marks, Edward A. Cuellar, Steven S. Miller, Eric Weitz
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Abstract
The invention relates to an improved method for synthesizing uranium hexamethoxide and new mixed methoxy uranium (VI) fluorides from uranium hexafluorides. Irradiation of the products of the invention in the vapor phase, with a pulsed CO.sub.2 gas laser leads to enrichment in the U-235 content of the isotopic mixture containing U-235 and U-238, the degree of enrichment depending upon the laser frequency employed.
Claims3
A process for synthesizing uranium hexamethoxide by reacting uranium hexafluoride with a methoxide having formula M (OCH.sub.3).sub.x wherein M is an electropositive metal of group 1A of the periodic table and x is 1, or M is a silicon residue having 1 to 3 alkyl radicals, and x is an integer from 1 to 3
- said method comprising the steps of:
- dissolving UF.sub.6 in a dry halogenated hydrocarbon solvent selected from the group consisting of chlorinated aliphatic solvents, chlorofluorinated aliphatic solvents and mixtures thereof cooled to below 0.degree. C.,
- suspending said methoxide in a dry halogenated hydrocarbon solvent selected form the group consisting of chlorinated aliphatic solvents, chlorofluorinated aliphatic solvents and mixtures thereof cooled to below 0.degree. C.,
- preparing a reaction mixture by gradually adding the solution of UF.sub.6 to the suspension of said methoxide and allowing said reaction mixture gradually to warm up to a temperature of about 0.degree. C.,
- separating a red solid reaction product from said halogenated hydrocarbon solvent, and washing said reaction product with a dry hydrocarbon solvent to provide a purified uranium hexamethoxide.
Dependencies are inferred from the claim text.