Catalyst for polymerizing olefins
AssigneeStauffer Chemical Company
InventorsRobert I. Mink, Ronald A. Epstein
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Abstract
A catalytic system for polymerizing olefins comprises: (a) a component containing an organoaluminum compound, and (b) a component containiong a titanium halide prepared by a process comprising: (i) intimately contacting a magnesium compound containing halogen or a manganese compound containing halogen with a carboxylic acid to produce an activated product, (ii) optionally treating the activated product with a phenol, and (iii) reacting the activated product, optionally treated with phenol, with a titanium halide compound. The invention also includes a process for preparing component (b) containing a titanium halide, the composition of component (b), and the use of the catalytic system for polymerizing olefins such as ethylene or propylene.
Claims30
A catalytic system for polymerizing olefins comprising:
- (a) a component containing an organoaluminum compound, and
- (b) a component containing a titanium halide obtained by a process comprising:
- (i) intimately contacting a magnesium compound containing halogen or a manganese compound containing halogen with a carboxylic acid to produce an activated product, and
- (ii) reacting the activated product with a titanium halide compound.
A component containing titanium halide of a catalytic system for polymerizing olefins prepared by a process comprising:
- (i) intimately contacting a magnesium compound containing halogen or a manganese compound containing halogen with a carboxylic acid to produce an activated product, and
- (ii) reacting the activated product with a titanium halide compound.
A process for producing a component containing titanium halide of a catalytic system for polymerizing olefins comprising:
- (a) intimately contacting a magnesium compound containing halogen or a manganese compound containing halogen with a carboxylic acid to produce an activated product, and
- (b) reacting the activated product with a titanium halide compound.
Dependencies are inferred from the claim text.