Passivation of metal contaminants on cracking catalyst with a lithium compound
AssigneeUop LLC
InventorHosheng Tu
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Abstract
A contaminating metal on cracking catalyst used for the cracking of hydrocarbons is passivated by contacting the catalyst with a lithium compound at passivation reaction conditions. The passivation may be effected in a separate passivation zone with an aqueous solution of a water soluble lithium compound or in the cracking zone by dissolving an oil soluble lithium compound in the feedstock. The amount of lithium deposited on the catalyst is from about 0.5 wt. % to about 1.25 wt. % on an elemental basis.
Claims11
A process for passivating a metal on fluidized cracking catalyst which has been contaminated with said metal due to the use of said catalyst in a fluidized cracking system and wherein said catalyst is cycled between a cracking zone, in which said catalyst is contacted at an elevated temperature with a hydrocarbon feedstock containing said metal contaminant which deposits on said catalyst, and a regeneration zone, in which carbon is oxidized and thereby removed from said catalyst, which process comprises contacting at least a portion of said catalyst at passivation reaction conditions with a lithium compound in an amount to deposit on the catalyst about 0.5 wt % to 1.25 wt % lithium on an elemental metal basis, to effect a passivation reaction between said metal and said lithium and the passivation of said metal contaminant so as to increase yield of C.sub.5.sup.+ and reduce the yield of hydrogen in said fluidized cracking system.
Dependencies are inferred from the claim text.