Control of pyrite addition in coal liquefaction process
AssigneeThe Pittsburg & Midway Coal Mining Co.
InventorsBruce K. Schmid, James E. Junkin
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Abstract
Pyrite addition to a coal liquefaction process (22, 26) is controlled (118) in inverse proportion to the calcium content of the feed coal to maximize the C.sub.5 --900.degree. F. (482.degree. C.) liquid yield per unit weight of pyrite added (110). The pyrite addition is controlled in this manner so as to minimize the amount of pyrite used and thus reduce pyrite contribution to the slurry pumping load and disposal problems connected with pyrite produced slag.
Claims15
A coal liquefaction process for increasing the amount of liquid product boiling in the range C.sub.5 --900.degree. F. (482.degree. C.), which comprises passing hydrogen and a feed slurry comprising a high calcium feed coal and a distillate solvent to a coal liquefaction zone, and adding pyrite to said feed slurry in inverse proportion to the calcium content of said feed coal.
A coal liquefaction process for producing a distillate liquid product which comprises passing hydrogen and a feed slurry comprising a calcium-containing feed coal containing at least 0.8 weight percent calcium based upon MF coal, recycle normally solid dissolved coal, recycle mineral residue and a distillate solvent to a coal liquefaction zone, measuring the calcium content of the ash of said feed coal and controlling the quantity of pyrite added to said feed slurry at a level determined by the concentration of calcium in said feed coal and in inverse proportion to said calcium content of said feed coal, reacting said slurry in a reaction zone at a temperature in the range of between about 399.degree. C. and about 482.degree. C. to dissolve said coal to form distillate liquid and normally solid dissolved coal, separating said reaction effluent into fractions, a first fraction comprising distillate boiling range liquid and a second fraction comprising normally solid dissolved coal and mineral residue, and recycling at least a portion of said distillate boiling range liquid, normally solid dissolved coal and mineral residue for mixing with said feed coal.
Dependencies are inferred from the claim text.