Electrochemical gas detection system
AssigneeRexnord Inc.
InventorGerardo A. Razumney
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AssigneeRexnord Inc.
InventorGerardo A. Razumney
Estimating the term…
There is disclosed an electrochemical gas detector system utilizing a polarized gas diffusion sensing electrode which is exposed to a gas mixture containing an electrochemically oxidizable or reducible gas, such as CO, H.sub.2, H.sub.2 S, SO.sub.2, NO, NO.sub.2 and CH.sub.4 which electrode has a suitable catalyst, such as platinum, iridium, ruthenium, gold, etc., as the active element at which the gas is electrochemically oxidized or reduced, a non-polarizable, reversible counter electrode constituted by a suitable redox couple, preferably of the type metal/metal salt, such as Ag/AgCl or metal/metal oxide, such as Hg/HgO, or metal oxide/metal salt, such as PbO.sub.2 /PbSO.sub.4, and a liquid electrolyte body in contact with both electrodes to constitute a complete electrochemical cell. A constant potential difference is applied between the electrodes which biases the sensing electrode to a selected portion of the electrochemical current-voltage curve for oxidation or reduction of the reducible gas. Means are provided for indicating current flowing between the electrodes as a measure of the concentration of the gas at the sensing electrode.
A polarographic electrochemical system for measuring the concentration of an electrochemically oxidizable gas in a gaseous sample consisting of (a) a gas diffusion sensing anodic electrode exposed to the sample gas and including an electrocatalyst, (b) a non-polarizable, reducible counter electrode, (c) an electrolyte in contact with both said electrodes, (d) means for applying a selected constant potential difference in the range of between 0.9 to 1.4 V versus a reversible hydrogen electrode in the same solution to said electrodes so as to bias said gas diffusion electrode into the limiting current plateau region of the current-potential curve where no parallel reactions interfere and in which the current is substantially independent of the potential for oxidation of the electrochemically oxidizable gas, and (e) means for measuring the current flowing between said electrodes as an indication of the electrochemically oxidizable gas in the gaseous sample.
A polarographic electrochemical device for measuring the concentration to at least 2 parts per million of an electrochemically reducible gas in a gaseous sample consisting of (a) a gas diffusion sensing anodic electrode exposed to the sample gas and including an electrocatalyst, (b) a non-polarizable oxidizable, counter electrode, (c) an electrolyte in contact with both said electrodes (d) means for applying a selected constant potential difference in the range of between 0.9 to 1.4 V versus reversible hydrogen electrode in same solution to said electrodes so as to bias said gas diffusion electrode solely into the limiting current plateau region of the current-potential curve for the cathodic reduction of the electrochemically reducible gas where no parallel reactions interfere and in which the current is substantially independent of the potential for oxidation of the electrochemically reducible gas, and (e) means for measuring the current flowing between said electrodes as an indication of the concentration of the electrochemically reducible gas in the gaseous sample.
A polarographic electrochemical gas measuring instrument for measuring CO concentration to at least 2 parts per million in a gaseous sample comprising:
Dependencies are inferred from the claim text.