Method of making photoconductive coating

In a method of depositing a wholly inorganic dielectric photconductive coating onto a substrate in which there is a provided a pressure vessel having therein target means comprising at least one target of the material to be deposited, there is provided a supply of substrate, there is an anode disposed in the vessel, means are provided for leading the substrate to pass over and in engagement with the anode during the sputtering process, there is an external source of radio frequency energy having electrical couplings to the anode, target means and to shielding arranged in the vicinity of the anode and target means, there is provided a supply of background gas including an inert ionizable gas and a second gas having at least one constituent for preventing disassociation of the compound during sputtering, there are provided means for establishing and maintaining a stable condition of sputtering plasma in the vessel between the target means and the anode, the steps of:

• A. coupling the external radio frequency energy source to the target means and the shielding so as to establish a high negative potential at the target means and ground potential at the shielding;
• B. arranging the anode electrically with respect to the external radio frequency energy source to provide a bias potential at the anode of about negative ten to negative 100 volts to produce a second dark space at the anode in addition to the usual first dark space at the cathode, the dark spaces being respectively on opposite sides of the sputtering pasma during sputtering;
• C. leading the substrate over and in engagement with the anode and at a location relative to the second dark space so that the said second dark space is between the sputtering plasma and substrate;
• D. providing temperature conditions during the sputtering at the anode to aid in the sputtering;
• E. permitting minute quantities of oxygen to be present in the vessel in an amount sufficient to form a barrier layer on the surface of the sputtered coating which includes oxygen in a combined form.
• F. introducing the background gas during the sputtering and
• G. permitting the minute quantities of oxygen remaining in the vessel to react with the outer surface of the sputtered coating to form a barrier layer thereon including oxygen in a combined form having a thickness of the order of 50 to 75 Angstrom units.

A method of making an electrophotographic member formed of a photoconductive coating on a substrate, the photoconductive coating being formed of a wholly inorganic dielectric compound which is microcrystalline of hexagonal, orderly, closely packed, highly uniform crystals having a crystal diameter less than 0.1 micron and a height equal to the thickness of the coating, the crystals all being arranged substantially vertically oriented relative to the plane of the substrate, the coating capable of accepting a charge of electrons at speeds of nanoseconds as well as at substantially slower speeds, such charge providing surface potential of the order of 10 volts per thousand Angstroms coating thickness, having a dark decay characteristic of surface potential versus time that drops off immediately after charging at a generally logarithmic rate, but with the rate of decay decreasing with time such that there remains substantially more than ten percent of the original maximum surface potential after several minutes with an absolute value sufficient to tone an image with an excellent grey scale, said member capable of being selectively discharged after being charged, by means of said radiation in any increment of area capable of being distinguished as finely as electronically from an immediately adjacent increment, said discharge occurring proportionally to the degree of radiation intensity to which said increment is subjected, the member being capable of total discharge, the increment assuming immediately after said discharge a decay characteristic of surface potential versus time which maintains proportionality of the said characteristics of all other increments of said member for a substantial period of time during which said increment can continue to be distinguished from all others, said method comprising the steps of

• (A) providing a conductive planar substrate,
• (B) depositing the photconductive coating in the form of a film of one of cadmium sulfide, a mixture of cadmium sulfide and zinc sulfide, zinc telluride and zinc sulfide on said conductive planar substrate by RF sputtering, and
• (c) forming a barrier layer including oxygen in a combined form on the exposed surface of said film, said barrier layer having a thickness of the order of less than 0.01 micron and a lateral surface resistivity of the order of 10.sup.20 ohms per square.