Hindered bis-phenol phenyl phosphites and synthetic resin compositions having enhanced stability to heat and light
AssigneeAdeka Argus Chemical Co., Ltd.
InventorsMotonobu Minagawa, Yutaka Nakahara
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AssigneeAdeka Argus Chemical Co., Ltd.
InventorsMotonobu Minagawa, Yutaka Nakahara
Estimating the term…
Hindered bis-phenol phenyl phosphites are provided having the structure: ##STR1## wherein: R is selected from the group consisting of alkyl having from one up to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; preferably, a bulky group such as iso, secondary or tertiary alkyl having from three to about ten carbon atoms; or cycloalkyl having six to twelve carbon atoms; R.sub.1 and R.sub.2 are each selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; and are preferably in a position ortho to a phenolic hydroxyl or phenoxy group, if available; R.sub.3 is alkylene having from one to about six carbon atoms; R.sub.4 is selected from the group consisting of alkylene, cycloalkylene, and aralkylene, the residue of a monohydric or polyhydric alcohol, having from one to about eighteen carbon atoms, and from none to three hydroxyl groups (originally one to four hydroxyl groups); Y is selected from the group consisting of a direct carbon to carbon bond; thio sulfur --S--; oxy oxygen --O--; alkylidene having from one to about six carbon atoms; and cycloalkylidene having from four to about eight carbon atoms; and n is 1, 2, 3, or 4, according to the valence of R.sub.4 ; as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of an organic phosphite of this class.
Hindered bis-phenol phenyl phosphites having the structure:
An olefin polymer composition in accordance with claim 24 wherein the polyolefin is polyethylene.
Dependencies are inferred from the claim text.